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HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 699Nanoscale Permanent Rings in Two- or...

Nanoscale Permanent Rings in Two- or Three-Dimensional Structure Constructed by the Self-Assembly of Copper(II)-Macrocyclic Complexes and Tetracyanonickelate(II)

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Abstract:

Self-assembly of polyazamacricyclic complexes of copper(II), [Cu(H₂L¹]⁴⁺, where L¹ = 1,8-bis(2-aminoethyl)-1,3,6,8,13-hexaazacyclotetradecane, and [Cu(H₂L²)]²⁺, where L² = 1,8-bis(4-butylic acid)-1,3,6,8,13-hexaazacyclotetradecane, [Ni(CN)₄]^2- produces two-dimensional permanent ring structure (1) and three-dimensional network structure (2), respectively, in crystalline solid. The geometry around copper(II) ion is an z-elongated octahedron (1) and square pyramid (2). Inter molecular hydrogen bonding of 1 produces one-dimensional ring chain and 2 produces one-dimensional zig-zag shape coordination polymer. Hydrogen bonding of neighboring chains of 1 produces two-dimensional permanent ring structure with a nanoscale area and that of 2 produces three-dimensional network structure having one-dimensional channels with nanoscale cross-section in crystalline solid.

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Materials Science and Chemical Engineering

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Periodical:

Advanced Materials Research (Volume 699)

Pages:

40-45

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.699.40

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Online since:

May 2013

Authors:

Chee Hun Kwak, Mee Chang, Min Chul Chung

Keywords:

Channel Structure, Coordination, Copper(II)-Macrocyclic Complexes, Hydrogen Bonding, Nanoscale, Permanent Ring, Tetracyanonickelate(II)

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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