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Synthesis and Properties of Ionogels Based on 1-vinyl-3-alkylimidazolium Tetrahalogenidoferrate (III) [VAIM][FeClnBr4-n] and PMMA

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Abstract:

The paramagnetic ionic liquid (IL) 1-vinyl-3-alkylimidazolium tetrahalogenidoferrate (Ⅲ) [VAIM][FeClnBr4-n] (A= n-butyl, n-pentyl, n-hexyl; n=3,4 or 2, 3,4.) has been used in the synthesis of paramagnetic [VAIM][FeClnBr4-n]/PMMA ionogels. The thermal stability for the ionogels increases significantly compared with [VAIM][FeClnBr4-n] and PMMA. Magnetic susceptibility measurements were carried out in the temperature range 1.8 K–300 K. The Curie–Weiss temperature is -0.989 K, -0.669 K and -0.169 K, respectively as the alkyl chain to 3 position of imidazole ring elongate. The magnetic properties are similar to those reported for the pure IL and the self-made [VAIM][FeClnBr4-n] and are not influenced by the incorporation of paramagnetic [VAIM][FeClnBr4-n] into the PMMA matrix. The magnetic ionogel is thus an interesting material combining the mechanical properties of the polyer with the functionality of the magnetic IL, such as magnetism.

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Periodical:

Advanced Materials Research (Volume 702)

Pages:

74-78

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.702.74

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Online since:

May 2013

Authors:

Yi Mei Tang, Xiao Ling Hu, Li Wei Qian, Ping Guan

Keywords:

1-vinyl-3-alkylimidazolium Tetrahalogenidoferrate (III), Ionogels, Magnetic Analysis, PMMA, Thermal Analysis

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