Synthesis and Characterization of a New Amino-Functionalized PMO Material

Abstract:

A new organic silicane which is bridged by a long amino-functionalized alkyl chain was prepared and used as the precursor in the synthesis of a series of PMO materials. The organic silicane was added into the reaction system in CH₂Cl₂ and the PMO materials were prepared by a simple stirring method under acidic condition, with a nonionic surfactantBrij 76 as template. To find the proper synthesis condition, the time of stirring and the proportion of organic silicane and TEOS were varied. Liquid and solid state NMR, X-ray diffraction (XRD) patterns, thermogravimetric analysis (TGA), transmission electron microscopy (TEM) and N₂-physisorption properties were used to characterize the structures.

• Periodical: Advanced Materials Research (Volumes 712-715)
• Pages: 271-279
• DOI: https://doi.org/10.4028/www.scientific.net/AMR.712-715.271
• Online since: June 2013
• Authors: Fei Ding, Shuang Xi Liu*
• Keywords: Characterization, Functional, PMO, Synthesis

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