Study on Electro-Catalytic Oxidation of Simulant Dye Wastewater Using Ti/SnO2-Sb2O3, Ti/SnO2-Sb2O3 /PbO2-Fe Anodes

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Abstract:

The Ti/SnO2-Sb2O3 and Ti/SnO2-Sb2O3/PbO2-Fe electrodes were prepared by thermal decomposition method. Using these two electrodes as anodes, two electro-catalytic oxidation processes were introduced to treat three simulant dye wastewaters, which respectively prepared by the dyes of acid orange II, alizarin red and methylene blue thrihydrate. The results show that these dyes with 100mg/L concentration were degraded by the optimal electrodes. When the current density was 75mA/cm2, the electrolyte concentration was 12g Na2SO4/L, and the degradation time was over 60 minutes, the removal ratio of acid orange II was around 80%, alizarin red was above 65%, and methylene blue thrihydrate was just 45% or so. The results that the removal rates of different dyes were different were explained based on the dyes chemistry structure. It was obtained that the chromophoric group of dye is more complex, the degradation process is more difficult.

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Advanced Materials Research (Volumes 726-731)

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2594-2598

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August 2013

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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[1] Changyong Jing, Xinsheng Zhang, Baoquan HUO, Liankai Zhang. in: Industrial Safety and Environmental Protection, Issue3,Vol. 34 (2008), pp.1-3.(In Chinese)

Google Scholar

[2] Xianyu Peng. in: Journal of Hunan Institute of Science and Technology(Natural Sciences), Issue1,Vol. 21 (2008), pp.54-56.(In Chinese)

Google Scholar

[3] Caishan Jiao, Yan Sun, Xueyan Men, Qing Wen. in: Environmental Science and Management, Issue1,Vol. 32 (2007), pp.107-110.(In Chinese)

Google Scholar

[4] Xiaomiao Wang, Fengping Hu, Jianwen Luo, Jing Li, Zhanmeng Liu. in:Journal of Zhongyuan University of Technology, Issue1,Vol. 20 (2009), pp.15-18.(In Chinese)

Google Scholar

[5] ZHANG L, JIA J, YING D et al. Electrochemical effect on denitrification in different microenvironment around anodes and cathodes. Research in Microbiology (0923 - 2508), 2005, 156(1): 88-92.

DOI: 10.1016/j.resmic.2004.07.006

Google Scholar

[6] Zhenhai Liang, Fuyuan Zhang, Caimei Fan, Haixia Miao. in:Rare Metal Materials and Engineering, Issue2,Vol. 36 (2007), pp.278-281.(In Chinese)

Google Scholar

[7] Feng Y, Cui Y, Logan B et al. Performance of Gd-doped Ti-based Sb-SnO2 anodes for electrochemical destruction of phenol. Chemosphere, 2008, 70(9): 1629-1636.

DOI: 10.1016/j.chemosphere.2007.07.083

Google Scholar

[8] Costa C R, Botta C M R, Espindola E L G,et al. Electrochemical Treatment of Tannery Wastewater Using DSA Electrodes[J]. Journal of Hazardous Materials(0304—3894),2008, 153(1): 616—627.

DOI: 10.1016/j.jhazmat.2007.09.005

Google Scholar

[9] Zaggout F R,Abu Ghalwa N. Removal of O-nitrophenol from Water by Electrochemical Degradation Using a Lead Oxide/Titanium Modified Electrode. Journal of Environmental Management(0301—4797), 2008, 86(1): 291-296.

DOI: 10.1016/j.jenvman.2006.12.033

Google Scholar

[10] ZHANG L, JIA J, YING D, et al. Electrochemical effect on denitrification in different microenvironment around anodes and cathodes. Research in Microbiology,2005, 156(1): 88-92.

DOI: 10.1016/j.resmic.2004.07.006

Google Scholar

[11] Feng Y, Cui Y, Logan B, et al. Performance of Gd-doped Ti-based Sb-SnO2 anodes for electrochemical destruction of phenol. Chemosphere,2008, 70(9): 1629-1636.

DOI: 10.1016/j.chemosphere.2007.07.083

Google Scholar