Synthesis of High-Quality MCM-41 Using Silica Fume as Silica Source

Ming Ming Li; Wen Jie Zhu; Wen Hui Ma; Yang Zhou; Ke Qiang Xie

doi:10.4028/www.scientific.net/AMR.734-737.2536

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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 734-737Synthesis of High-Quality MCM-41 Using Silica Fume...

Synthesis of High-Quality MCM-41 Using Silica Fume as Silica Source

Abstract:

The high-quality MCM-41 was synthesized from silica fume with Citric acid and cetyltrimethylammonium bromide (CTAB) as template agents. Silica fume entered into liquid system in silicate and matched with CTA⁺. Mesoporous phase formed with the help of Citric and PEG-6000 in an acidic process followed. The structure and morphology of mesoporous silica material so-prepared was investigated based on the analysis of X-ray diffraction (XRD), N₂ sorption/desorption (BET) and transmission electron microscopy (TEM). The results indicated that MCM-41 was successfully prepared by substituting silica fume for the traditional silica source of tetraethyl orthosilicate, and the MCM-41 displayed high quality with the pore sizes 4.3 nm, the BET areas 1058 m²/g, the total pore volume 0.862 cm³/g.

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Periodical:

Advanced Materials Research (Volumes 734-737)

Pages:

2536-2540

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.734-737.2536

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Online since:

August 2013

Authors:

Ming Ming Li*, Wen Jie Zhu, Wen Hui Ma, Yang Zhou, Ke Qiang Xie

Keywords:

Citric Acid (CA), Hydrothermal Synthesis, MCM-41, Silica Fume (SF), Two-Stage Method

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References

[1] C.T. Kresge, M.E. Leonowica, W.J. Roth and J.S. Beck: Nature Vol. 710-712 (1992), p.359

Google Scholar

[2] J.S. Beck, J.C. Vartuli, M.E. Leonowica, C.T. Kresge, K.D. Schiminitt, C.T.W. Chu, D.H. Olson, E.W. Sheppard, S.B. McCullen, J.B. Higgins and J.L. Schlenker: J. Am. Chem. Sco Vol. 114 (1992), p.10834

DOI: 10.1021/ja00053a020

Google Scholar

[3] A. Stein: Adv. Mater, Vol. 15 (2003), p.763

Google Scholar

[4] F.de. Clippel, A. Harkiolakis, T. Vosch, X. Ke, L. Giebeler, S. Oswald, K. Houthoofd, J. Jammaer, G.V. Tendeloo, J.A. Martens, P.A. Jacobs, G.V. Baron, B.F. Sels and J.F.M. Densyer: Micropor. Mesopor. Mat. Vol. 114 (2011) p.120

DOI: 10.1016/j.micromeso.2011.04.003

Google Scholar

[5] G.H. Hou, J.H. Luo and J.W. Chen, "Synthesis of Ordered Mesoporous Silica from Rice Hush Ash", Journal of Materials Science and Engineering Vol. 24 (2006), p.328

Google Scholar

[6] C. Ulrike，S.Ferdi: Microporous and Mesoporous Mater.Vol,27(1999),p.131

Google Scholar

[7] S.A. Bagshaw, E. Prouzet and T.J. Pinnavaia: Science. Vol. 269 (1995), p.1242

Google Scholar

[8] Q.S. Huo, D.I. Margolese and G.D. Stucky: Chem. Mater.Vol. 8 (1996), p.1147

Google Scholar