Geochemistry of Sulfur in Extract from Hedong Coal Mine, China

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Abstract:

The organosulfur compounds in the extract of the unusually organic sulfur rich of Hedong coal mine had been identified by gas chromatography and mass spectrometry. There are two series organosulfur compounds (OSC) were detected in the extract, they are benzonaphthothiophen and dibenzothiophene and the content of methylbiphenyl is overwhelming advantages in the biphenyl series. It demonstrates that the coal was formed in alkaline environment. The coal was formed in a reduction environment generally but there are exceptions, the samples HD9-2 and HD10-13 which have the value of Pr/Ph was 3.52 and 4.05 and So/St in sample HD9-2 was 78.82%, 73.08% in sample HD10-13 respectively . It show that the coal suffer strong oxidation and there are no good correlation between the content of organic sulfur and the oxidation environment.

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Periodical:

Advanced Materials Research (Volumes 734-737)

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89-94

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August 2013

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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[1] Chen-Lin Chou. Sulfur in Coals:A Review of Geochemistry and Origins. International Journal of Coal Geology.Vol.100(2012),pp.1-13

DOI: 10.1016/j.coal.2012.05.009

Google Scholar

[2] Yuzhuang Sun. Geochemical evidence for multi-stage base metal enrichment in Kupferschiefer.(1996)

Google Scholar

[3] Kenneth E. Peters and J. Michael Moldowan. The biomarker guide: interpreting molecular fossils in petroleum and ancient sediments.Petroleum Industry Press.(1995)

Google Scholar

[4] Dujie Hou,Linye Zhang.Illustrated handbook of oil and gas geochemistry. Petroleum Industry Press.2003,p.129 (In Chinese)

Google Scholar

[5] Yanqing Xia, Chunjiang Wang, Qianxiang Meng etc. Formation Mechanism of biphenyl and benzonaphthothiophen series compounds. Science in China(series D).Vol.29(1999),p.262 (In Chinese)

Google Scholar