Hydrolysis of BNPP Catalyzed by the Dodecyliminodiacetate Nickel (II) Complexes

Abstract:

One novel dodecyliminodiacetate nickel (II) complex were synthesized and characterized, and these complexes were used as mimic hydrolytic in catalytic hydrolysis of bis (p-nitrophenyl) phosphate (BNPP). The analysis of specific absorption spectra of the hydrolytic reaction systems indicated that the catalytic hydrolysis involved the key intermediates formed by BNPP with nickel (II) complexes. The kinetic parameter of BNPP catalytic hydrolysis has been calculated and the activation energy for the catalytic hydrolysis is 95.26kJ·mol^-1.

• Periodical: Advanced Materials Research (Volume 746)
• Pages: 123-127
• DOI: https://doi.org/10.4028/www.scientific.net/AMR.746.123
• Online since: August 2013
• Authors: Shen Xin Li, Wei Hu, Ying Wang, Song Wu
• Keywords: Catalytic Kinetics, Dodecy Liminodiacetate Nickel (II) Complexe, Mimic Hydrolase, Phosphate Esters Hydrolysis

References

[1] Rick. L. Hegg , Judith N. Burstyn. Coordination Chemistry Reviews Vol. 173(1998), p.133.

[2] Li, J. Z., Feng, F. M., Xu, B., Jiang, W. D., Qin, S.Y. Transition Met. Chem Vol. 33 (2008), p.655.

[3] Pang, Q. H., Zang, R. R., Kang, G. L., Li, J. M., Hu. W., Meng, X. G., Zeng X.C. J. Disper. Sci. Technol. Vol. 27( 2006), p.671.

[4] Meng,Y., Jiang, F. B., Hu,W., Meng, X.G., Yu, X. Q., Zeng, X. C. J. Disper. Sci. Technol. Vol. 27 (2006), p.15.

[5] Jiang, W. D., Xu, B., Lin, Q., Li, J. Z., Liu, F., Zeng, X.C., Chen, H. Colloids Surf. A: Physicochem. Eng. Aspects Vol. 315(2008), p.103.

[6] Xu, B., Jiang, W. D., Li, J.Z. J. Disper. Sci. Tech. Vol. 29(2008), p.1319.

[7] Li,J.Z., Li,H.B., Feng F.M., Xie,J. Q., Li, S. X., Zhou, B., Qin, S.Y. Chin. J. Chem. Vol. 23(2005), p.678.

[8] Xie, J.Q., Li, J., Sang, X.M., Wan, M., Chen, G.X. Reaction Kinetics and Mechanism Vol. 31(2006), p.189.

[9] Jiang, F.B., Jiang, B.Y., Cao Y.S., Meng, X.G., Yu, X.Q., Zeng, X.C. Colloid. Surface. A. Vol. 254(2005), p.91.

[10] Xie, J.Q., Chen, Y., Yan, H., Chen, G.X., Ou, Z.W., Xie, B. Reaction Kinetics and Mechanism Vol. 31 (2006), 31(1): p.29.

[11] Jiang, W.,D., Xu. B., Li, J.Z., Lin, Q., Zeng, X.C., Chen, H. Reaction Kinetics and Mechanism, Vol. 31(2006), p.11.

[12] Zhang, Y., Xie, J.Q., Li, C., Shang, H.L., Wang, M. Reaction Kinetics and Mechanism, Vol. 33(2008), p.349.

[13] Kramer, R. Coord. Chem. Rev. Vol. 182 (1999), p.243.

[14] Jurek, P., Martell, A.E. Inorg. Chim. Acta. Vol. 287 (1999), p.47.

[15] Roigk, A.; Yescheulova, O. V.; Schneider H. J. Org. Lett. Vol. 1 (1999), p.833.

[16] Hu, W., Wang,Y., Li, J. Z., Du, J., Meng, X.G., Hu, C.W., Zeng, X. C. Chin. J. Chem. Vol. 24 (2006), p.1498.

[17] Hu, W., Wang Y., Yan, J., Li, J.Z., Meng, X.G., Hu, C.W., Zeng, X.C. J. Dispersion Sci. Technol. Vol. 8 ( 2006), p.1085.

[18] Wanger, M. R., Walker, F. A. Inorg. Chem. Vol. 22 (1983), p.3021.

[19] Itoh, T., Hisada, H., Usui,Y. Inorg. Chim. Acta. Vol. 283 (1998) , p.51.

[20] Young, M. J., Wahnon, D., Hynes, R. C., Chin, J. J. Am. Chem. Soc. Vol. 117 (1995), p.9441.