Fabrication and Characterization of Poly(vinyl Alcohol)/Functionalized Graphene Oxide Nanofibers Produced by Electrospinning Method

Article Preview

Abstract:

A series of poly (vinyl alcohol) (PVA)/functionalized graphene oxide (FGO) nanofibers with low feeding ratios of FGO to PVA were fabricated by electrospinning method. In this study, the prepared PVA/FGO nanocomposites were dispersed in water phase followed by electrospinning treatment under different operational parameters (i.e., applied voltage, feeding rate and FGO contents) to give nanofibers of various diameters and morphologies. The morphology, diameter and structure of electrospun nanofibers and FGO were investigated by Fourier transform infrared (FT-IR) spectroscopy, X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), (TGA) and differential scanning calorimetry (DSC). SEM images showed that the morphologies of the nanofibers were improved by the incorporation of FGO at a low loading content (e.g., 0.1~0.5 wt %) as compared to pure electrospun PVA. The crystallinity and thermal stability of PVA/FGO nanofibers were also studied.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

405-408

Citation:

Online since:

August 2013

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2013 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] Kuila, T.; Bose, S.; Mishra, A. K.; Khanra, P.; Kim, N. H.; Lee, J. H., Chemical functionalization of graphene and its applications. Prog Mater Sci 2012, 57 (7), 1061-1105.

DOI: 10.1016/j.pmatsci.2012.03.002

Google Scholar

[2] Zhang, C. X.; Yuan, X. Y.; Wu, L. L.; Han, Y.; Sheng, J., Study on morphology of electrospun poly(vinyl alcohol) mats. Eur Polym J 2005, 41 (3), 423-432.

DOI: 10.1016/j.eurpolymj.2004.10.027

Google Scholar

[3] Liang, J. J.; Huang, Y.; Zhang, L.; Wang, Y.; Ma, Y. F.; Guo, T. Y.; Chen, Y. S., Molecular-Level Dispersion of Graphene into Poly(vinyl alcohol) and Effective Reinforcement of their Nanocomposites. Adv Funct Mater 2009, 19 (14), 2297-2302.

DOI: 10.1002/adfm.200801776

Google Scholar

[4] Marcano, D. C.; Kosynkin, D. V.; Berlin, J. M.; Sinitskii, A.; Sun, Z. Z.; Slesarev, A.; Alemany, L. B.; Lu, W.; Tour, J. M., Improved Synthesis of Graphene Oxide. Acs Nano 2010, 4 (8), 4806-4814.

DOI: 10.1021/nn1006368

Google Scholar

[5] Bose, S.; Kuila, T.; Mishra, A. K.; Kim, N. H.; Lee, J. H., Dual role of glycine as a chemical functionalizer and a reducing agent in the preparation of graphene: an environmentally friendly method. J Mater Chem 2012, 22 (19), 9696-9703.

DOI: 10.1039/c2jm00011c

Google Scholar