Superhydrophobic Silicon Surface with Micro/Nanocomposite Structure Formed by 2-Step Wet Etching

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The micro/nanocomposite structure on silicon surface was formed by a simple 2-step chemical etching with a potassium hydroxide anisotropic etching and a stain etching in order to obtain a superhydrophobic silicon surface. Micro-sized pyramids structure was formed in a mixture of 3 wt.% potassium hydroxide with 8 vol.% isopropyl alcohol solution at 80C for 60 min. The formation of the nanosized structure was performed by stain etching at room temperature using nitric acid (HNO3) / hydrofluoric acid (HF) aqueous solutions. The silicon surface had the superhydrophobic surface. The contact angle was measured and the maximum value was 167o for the condition of second etching with HF : HNO3 : H2O = 11 : 1 : 3.

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542-546

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August 2013

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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[1] M. Nosonovsky, B. Bhushan, Roughness optimization for biomimetic superhydrophobic surfaces, Microsyst. Technol. 11 (2005) 535-549.

DOI: 10.1007/s00542-005-0602-9

Google Scholar

[2] M. Nosonovsky, B. Bhushan, Wetting of rough three-dimensional superhydrophobic surfaces, Microsyst. Technol. 12 (2006) 273-281.

DOI: 10.1007/s00542-005-0067-x

Google Scholar

[3] A.W. Adamson, Physical Chemistry of Surfaces, 6th ed., Wiley, New York, (1982).

Google Scholar

[4] A.B.D. Cassie, S. Baxter, Wettability of porous surfaces, Trans. Faraday Soc. 40 (1944) 546-551.

DOI: 10.1039/tf9444000546

Google Scholar

[5] K. Nishioka, T. Sueto, K. Yoshino, N. Saito, Water-repellent silicon surface with nanostructure formed by catalysis of single nanosized silver particle, Jpn. J. Appl. Phys. 50 (2011) 128003.

DOI: 10.7567/jjap.50.128003

Google Scholar

[6] X. Li, P.W. Bohn, Metal-assisted chemical etching in HF/H2O2 produces porous silicon, Appl. Phys. Lett. 77 (2000) 2572-2574.

DOI: 10.1063/1.1319191

Google Scholar

[7] S. Koynov, M.S. Brandt, M. Stutzmann, Black nonreflecting silicon surfaces for solar cells, Appl. Phys. Lett. 88 (2006) 203107.

DOI: 10.1063/1.2204573

Google Scholar

[8] K. Tsujino, M. Matsumura, Y. Nishimoto, Texturization of multicrystalline silicon wafers for solar cells by chemical treatment using metallic catalyst, Sol. Energy Mater. Sol. Cells 90 (2006) 100-110.

DOI: 10.1016/j.solmat.2005.02.019

Google Scholar

[9] X. Li, B.K. Tay, P. Miele, A. Brioude, D. Cornu, Fabrication of silicon pyramid/nanowire binary structure with superhydrophobicity, Appl. Surf. Sci. 255 (2009) 7147–7152.

DOI: 10.1016/j.apsusc.2009.03.047

Google Scholar

[10] P. Menna, G. Di Francia, V. La Ferrara, Porous silicon in solar cells: A review and a description of its application as an AR coating, Sol. Energy Mater. Sol. Cells 37 (1995) 13-24.

DOI: 10.1016/0927-0248(94)00193-6

Google Scholar

[11] J. Xiao, L. Wang, X. Li, X. Pi, D. Yang, Reflectivity of porous-pyramids structured silicon surface, Appl. Surf. Sci. 257 (2010) 472–475.

DOI: 10.1016/j.apsusc.2010.07.014

Google Scholar