Paper Titles

Relationship between Fractal Dimension and Structure of Nonwovens
p.1176

The Application of Thermal Analysis to Research on Energetic Materials
p.1180

Research on Appropriate Additives of Recycling Ladle Lining Materials for Al₂O₃-SiC-C Iron Runner Castable
p.1184

The Research Status of Spongy Composite in the Wound Dressings
p.1188

N-Allyl-N-Methyl Piperidinium Bis(Trifluoromethanesulfonyl) Imide as a Co-Solvent in Li-Ion Batteries
p.1194

First-Principles Calculation of the Electronic Structure of SrTiO₃
p.1199

Syntheses and Characterization of Chiral Branched-Arm Liquid Crystals-Basing on Isosorbide as Chiral Core
p.1203

Thickness-Modulated One-Dimensional Periodic Phononic Crystal
p.1207

Phase Change Materials Applied in Thermal Design
p.1211

HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 750-752N-Allyl-N-Methyl Piperidinium...

N-Allyl-N-Methyl Piperidinium Bis(Trifluoromethanesulfonyl) Imide as a Co-Solvent in Li-Ion Batteries

Article Preview

Abstract:

Mixtures of an ionic liquid (IL) with organic solvents and a lithium salt have been studied in order to develop new electrolytes for lithium-ion cells with enhanced safety profiles. In this work, N-allyl-N-methylpiperidinium bis (trifluoromethanesulfonyl) imide (PP_1ATFSI) was synthesized and characterized to exhibit high decomposition temperature and wide electrochemical stability window. The evaluation of the coin cell LiFePO₄/Li with the mixed electrolyte based on PP_1ATFSI with 0.35mol/kg LiTFSI, and 30 wt% VC/DMC (1:1) shows a nice reversibility and cycle performances. All above prove that PP_1ATFSI is one of the most promising safety electrolytes of Li-ion battery.

You might also be interested in these eBooks

Advanced Engineering Materials III

Info:

Periodical:

Advanced Materials Research (Volumes 750-752)

Pages:

1194-1198

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.750-752.1194

Citation:

Cite this paper

Online since:

August 2013

Authors:

Jun Hui Zhou, Cui Hua Li, Bin Bin Yang

Keywords:

Electrolyte, Ionic Liquid (IL), Lithium-Ion Battery, Safety

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

© 2013 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] Dunn B, Kamath H, Tarascon J-M. Electrical energy storage for the grid: A battery of choices. Science (New York, NY), 2011, 334(6058): 928-935.

DOI: 10.1126/science.1212741

[2] Kim T-H, Park J-S, Chang SK, et al. The current move of lithium ion batteries towards the next phase. Advanced Energy Materials, 2012, 2(7): 860-872.

DOI: 10.1002/aenm.201200028

[3] Li J, Daniel C, Wood D. Materials processing for lithium-ion batteries. Journal of Power Sources, 2011, 196(5): 2452-2460.

DOI: 10.1016/j.jpowsour.2010.11.001

[4] Thackeray MM, Wolverton C, Isaacs ED. Electrical energy storage for transportation—approaching the limits of, and going beyond, lithium-ion batteries. Energy & Environmental Science, 2012, 5(7): 7854-7854.

DOI: 10.1039/c2ee21892e

[5] Goodenough JB, Kim Y. Challenges for rechargeable li batteries †. Chemistry of Materials, 2010, 22(3): 587-603.

[6] Etacheri V, Marom R, Elazari R, et al. Challenges in the development of advanced li-ion batteries: A review. Energy & Environmental Science, 2011, 4(9): 3243-3243.

DOI: 10.1039/c1ee01598b

[7] Lalia BS, Yoshimoto N, Egashira M, et al. A mixture of triethylphosphate and ethylene carbonate as a safe additive for ionic liquid-based electrolytes of lithium ion batteries. Journal of Power Sources, 2010, 195(21): 7426-7431.

DOI: 10.1016/j.jpowsour.2010.05.040

[8] Jin J, Li HH, Wei JP, et al. Li/lifepo4 batteries with room temperature ionic liquid as electrolyte. Electrochemistry Communications, 2009, 11(7): 1500-1503.

DOI: 10.1016/j.elecom.2009.05.040

[9] Schaefer JL, Lu Y, Moganty SS, et al. Electrolytes for high-energy lithium batteries. Applied Nanoscience, 2011, 2(2): 91-109.

DOI: 10.1007/s13204-011-0044-x

[10] Reiter J, Nadherna M. N-allyl-n-methylpiperidinium bis(trifluoromethanesulfonyl)imide—a film forming ionic liquid for graphite anode of li-ion batteries. Electrochimica Acta, 2012, 71(22-26.

DOI: 10.1016/j.electacta.2012.03.088

[11] Appetecchi GB, Scaccia S, Tizzani C, et al. Synthesis of hydrophobic ionic liquids for electrochemical applications. Journal of The Electrochemical Society, 2006, 153(9): A1685-A1685.

DOI: 10.1149/1.2213420

[12] Xu J, Yang J, NuLi Y, et al. Additive-containing ionic liquid electrolytes for secondary lithium battery. Journal of Power Sources, 2006, 160(1): 621-626.

DOI: 10.1016/j.jpowsour.2006.01.054

[13] Xiang HF, Yin B, Wang H, et al. Improving electrochemical properties of room temperature ionic liquid (rtil) based electrolyte for li-ion batteries. Electrochimica Acta, 2010, 55(18): 5204-5209.

DOI: 10.1016/j.electacta.2010.04.041

[14] Shiro Seki YOYKHMAUYMHTMWKHSTMHNT. Imidazolium-based room-temperature ionic liquid for lithium secondary batteries. Pdf. Journal of The Electrochemical Society, 2007, 154(3): A173-A177.

DOI: 10.1149/1.2426871

[15] Yide Jin SFMCLYKTS-iH. Properties and application of ether-functionalized trialkylimidazolium ionic liquid electrolytes for lithium battery. Pdf. Journal of Power Sources, 2013, 226(210-218.

DOI: 10.1016/j.jpowsour.2012.10.076