Synthesis and Swelling Behaviors of Wheat Straw Cellulose-g-Poly (Potassium Acrylate)/PDMDAAC Amphoteric Semi-IPNs Superabsorbent Resin

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A novel superabsorbent resin (SAR) which was called wheat straw cellulose-g-poly (potassium acrylate)/poly-diallyl dimethyl ammonium-chloride (WSC-g-PKA/PDMDAAC) semi-interpenetrating polymer networks (semi-IPNs) amphoteric SAR was synthetized by graft polymerization and semi-interpenetrating technology with the present of initiator and crosslinker. The effects of AA, PDMDAAC and crosslinker content on water absorbency of semi-IPNs SAR were studied. The semi-IPNs SAR prepared under optimized synthesis condition gave the best water absorption of 210.57 g/g in distilled water and 22.13 g/g in 0.9 wt% NaCl solution. In addition, the results showed that high water absorbency appeared from pH 4 to 9, and the effect of the salt ions in the swelling capacity was Al3+ > Ca2+ > Mg2+ > K+ > Na+.

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Advanced Materials Research (Volumes 750-752)

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1415-1419

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August 2013

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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[1] L. H. Sperling: Polymer 18 (1984) 3593-3595.

Google Scholar

[2] A. Bhatnagar and M. Sillanpää: A review. Chem. Eng. J. 157 (2010) 277 − 296.

Google Scholar

[3] T. S. Anirudhan,P. S. Suchithra, P. Senan, and A. R. Tharun: Ind. Eng. Chem. Res. 51 (2012) 4825− 4836.

Google Scholar

[4] F. Wu, Y. Zhang, L. Liu and J.M. Yao: Carbohydr. Polym. 87 (2012) 2519–2525.

Google Scholar

[5] Q. Chang, Y. Chen and X. Han: Acta Scientiae Circumstantiae 2 (2000) 168–172.

Google Scholar

[6] K. Zhong, X. L. Zheng, X. Y. Mao, Z. T. Lin and G. B. Jiang: Carbohydr. Polym. 90 (2012) 820-826.

Google Scholar

[7] Z. Liu, Y. Miao and Z. Wang: Carbohydr. Polym. 77 (2009) 131–135.

Google Scholar

[8] X. Li, S.M. Xu, J.D. Wang, X.Z. Chen and S. Feng: Carbohydr. Polym. 75 (2009) 688–693.

Google Scholar

[9] P. Lanthong, R. Nuisin and S. Kiatkamjornwong: Carbohydr. Polym. 66 (2006) 229–245.

Google Scholar

[10] Y. Bao, J. Z. Ma and N. Li: Carbohydr. Polym. 84 (2011) 76–82.

Google Scholar