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Synthesis and Swelling Behaviors of Wheat Straw Cellulose-g-Poly (Potassium Acrylate)/PDMDAAC Amphoteric Semi-IPNs Superabsorbent Resin
Abstract:
A novel superabsorbent resin (SAR) which was called wheat straw cellulose-g-poly (potassium acrylate)/poly-diallyl dimethyl ammonium-chloride (WSC-g-PKA/PDMDAAC) semi-interpenetrating polymer networks (semi-IPNs) amphoteric SAR was synthetized by graft polymerization and semi-interpenetrating technology with the present of initiator and crosslinker. The effects of AA, PDMDAAC and crosslinker content on water absorbency of semi-IPNs SAR were studied. The semi-IPNs SAR prepared under optimized synthesis condition gave the best water absorption of 210.57 g/g in distilled water and 22.13 g/g in 0.9 wt% NaCl solution. In addition, the results showed that high water absorbency appeared from pH 4 to 9, and the effect of the salt ions in the swelling capacity was Al3+ > Ca2+ > Mg2+ > K+ > Na+.
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1415-1419
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August 2013
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© 2013 Trans Tech Publications Ltd. All Rights Reserved
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