Preparation and Property Studies of Core-Shell Structure Polyacrylate Microspheres for Plastisol

Xiao Li Song; Zeng Hui Cheng; Ying Chen; Yu Zhi Xu; Chun Peng Wang

doi:10.4028/www.scientific.net/AMR.750-752.797

Paper Titles

Effect of Melt Intensive Homogenization on Solidification Microstructure of 7075 Aluminium Alloy by Twin-Screw Stirring
p.771

Valence Electron Structures Analysis on Relationship of Cu Physical or Mechanical Properties and Vacancy
p.776

Synthesis and Properties of a Novel Polymeric Phosphate Flame Retardant
p.785

The Research Method and Performance Analysis of the Curing Process of E51-593 System and TDE85-593 System
p.789

Preparation and Property Studies of Core-Shell Structure Polyacrylate Microspheres for Plastisol
p.797

Miscibility Study of Chitosan and Methylcellulose Blends
p.802

Study on the Effect of the Temperature Rise of Rubber Compound on Tread Rubber Quality during Mixing Process
p.806

Plastics: The Discovery in the World and Development in China
p.811

Research on Mechanical Properties, Compatibility, Flame Retardancy, Hot-Air Ageing Resistance of Hydrogenated Nitrile-Butadiene Rubber/Chloroprene Rubber Blends
p.816

HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 750-752Preparation and Property Studies of Core-Shell...

Preparation and Property Studies of Core-Shell Structure Polyacrylate Microspheres for Plastisol

Abstract:

Soft-core/hard-shell polyacrylate latex with different cross-linking degree and shell thickness were prepared by semi-continuous seed emulsion copolymerization .The size, size distribution and morphology of latex particles were characterized using dynamic light scattering (DLS) and scanning electron microscopy (SEM). The properties of plastisol were investigated by testing their dynamic viscoelasticity and storage stability as well as the mechanical properties. The results showed that the latex particles always keep regular spherical structure throughout the polymerization process; Dynamic viscoelasticity of plasticized system with different cross-linking degree however had little changed. The mechanical properties of the plastigels could be improved by increasing the thickness of shell.

You might also be interested in these eBooks

View Preview

Info:

Periodical:

Advanced Materials Research (Volumes 750-752)

Pages:

797-801

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.750-752.797

Citation:

Cite this paper

Online since:

August 2013

Authors:

Xiao Li Song, Zeng Hui Cheng, Ying Chen, Yu Zhi Xu, Chun Peng Wang*

Keywords:

Core-Shell, Plastisol, Polyacrylate

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

Citation:

* - Corresponding Author

References

[1] Soucek MD (1996) Prog Org Coat 28: 313.

Google Scholar

[2] Okubo M, Yamaguch i S, Matsumoto T. J. App1. Polym. Sci : Polym. Lett. 1986 ( 31 ): 1075.

Google Scholar

[3] TOSHIHIRO KASAI N. Acrylic polymer fine particles and plastisol using the same: US: US 6433048, 2002-08-13.

Google Scholar

[4] KASAI T C. Fine acrylic polymer particles and plastisol containing the same. US: EP1162217, 2008-12-24.

Google Scholar

[5] Nakajima N, Sadeghi MR, Kyu T(1990) J Appl Polym Sci 41: 889.

Google Scholar

[6] Nakajima N, Daniels CA (1980) J Appl Polym Sci 25: (2019).

Google Scholar

[7] Rebrovic JA (2000) Metal Finishing 98: 124.

Google Scholar

[8] Guojun Wang, Jing Wang . Study on the Preparation and Properties of Core-Shell Acrylate Emulsion for the Automobil [J]. Shanghai Coating , 2011, 49(8): 1-4.

Google Scholar

[9] Zenghui Cheng, Mingming Zhang, Chunpeng Wang. Rheological Properties of Plasticized Polyacrylate Microspheres [J]. Polymer Materials Science and Engineering, 2012, 28(009): 95-98.

Google Scholar

[10] M. Lu, H. Keskkula, D.R. Paul, Polymer 37 (1996) 125.

Google Scholar

[11] V. Nelliappan, M.S. El-Aasser, A. Klein, E.S. Daniels, J. Appl. Polym. Sci. 65 (1997) 581.

Google Scholar

[12] Jimin Ren, Ning Zhang, Yongzhou Bao. Synthesis of ACR Impact Modifier with PVC Shell and Its Toughening Eficiency on PVC [J]. China Plastics Industry, 2011, 39(2): 90-93.

Google Scholar