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Synthesis and Properties of a Novel Polymeric Phosphate Flame Retardant

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Abstract:

A novel polymeric phosphate flame retardant (PFR-P) was synthesized from 1-oxo-4-hydroxymethyl-2,6,7-trioxa-1-phosphbicyclo [2.2.octane (pentaerythritol phosphate, PEPA), POCl3 and bisphenol S. Phosphorus was bonded both in the main chain and in the pendant group of flame-retardant polymer molecule, reached a content of 13.1%. And sulfur content was 6.75%. The thermal stability was investigated by TGA, and the results showed that the initiative decomposition temperature was 334°C with 41.1% charring residue at 500°C under air. The high phosphorus and sulfur content contributes an excellent flame retardancy to PC/ABS without a considerable decrease of mechanical properties. It is a potential flame retardant for other polymer systems.

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Periodical:

Advanced Materials Research (Volumes 750-752)

Pages:

785-788

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.750-752.785

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Online since:

August 2013

Authors:

Li Yan

Keywords:

Flame Retardant, PC/ABS, Phosphorus, Polymeric, Synthesis

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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References

[1] S.Y. Lu, I. Hamerton, Prog. Polym. Sci. 2002, 27 , 1661.

Google Scholar

[2] S.V. Levchik, E.D. Weil, Polym. Int. 2008, 57, 431.

Google Scholar

[3] D. W. Allen, E. C. Anderton, C. Bradley, Polym. Degrad. Stab. 1995, 47, 67-72.

Google Scholar

[4] Y. Halpern, M. M. Denna, R.H. Niswander, Ind. Eng. Chem. Prod. Res. Dev. 1984, 23, 233.

Google Scholar

[5] X. Li, Y.X. Ou, Y.S. Shi, Polym. Degrad. Stab. 2002, 77, 383.

Google Scholar

[6] F. Gao, L.F. Tong, Z.P. Fang, Polym. Degrad. Stab. 2006, 91, 1295.

Google Scholar

[7] H.Y. Ma, L. F. Tong, Z.B. Xu, et al, Polym. Degrad. Stab. 2007, 92, 720.

Google Scholar

[8] D.M. Ban , Y.Z. Wang, B. Yang, Eur. Polym. J. 2004, 40, (1909).

Google Scholar

[9] Y.L. Chang, Y.Z. Wang, D.M. Ban, Macromol. Mater. Eng. 2004, 289, 703.

Google Scholar

[10] D.Y. Wang, X.G. Ge, Y.Z. Wang, et al, Macromol. Mater. Eng. 2006, 291, 638.

Google Scholar

[11] W. S. Wadsworth, W. D. Emmons, J. Am. Chem. Soc. 1962, 84, 610.

Google Scholar

[12] J.R. Ebdon, D. Price, B.J. Hunt, et. al, Polym. Degrad. Stab. 2000, 69, 267.

Google Scholar

[13] D. W. Krevelen, Polymer 1975, 16, 615.

Google Scholar

[14] S.V. Levchik, E.D. Weil, Polym. Int. 2005, 54, 981.

Google Scholar

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