FT-IR Study of Propylene Oxide Adsorption on Metal Oxides

Wen Yu Zhang; Jing Guo Li; Feng Ma; Xiao Yong Yang

doi:10.4028/www.scientific.net/AMR.781-784.169

Paper Titles

Hydrothermal Synthesis Hollow BiVO₄ Photocatalysts
p.147

Synthesis of Nanocrystalline TiO₂ by NH₄F-Assisted Low Temperature Hydrolysis Method and its Photocatalytic Ability for Rhodamine B
p.152

Particle Coating of Talc with TiO₂: Synthesis, Characterization and Photo Catalytic Degradation of Methylene Blue
p.157

An Eco-Friendly Catalytic Route for One-Pot Synthesis of Phenols from Aromatics and Hydroxylamine
p.163

FT-IR Study of Propylene Oxide Adsorption on Metal Oxides
p.169

Preparation of the Liquid Crystal Intermediate via Bromo-Reaction of Phenylacetylene and N-Bromosuccinimide
p.174

Spectroscopic Studies of Pyrene Adsorbed to Titanium Dioxide from Water- Alcohol Mixtures
p.178

Catalytic Oxidation of o-chlorotoluene to o-chlorobenzaldehyde by Vanadium Doped Anatase Mesoporous TiO₂
p.182

Effects of Different Pretreatment Pressures on the Catalytic Performance of Catalyst Derived from (CO)₆Co₂CC(COOH)₂ for Fischer-Tropsch Synthesis
p.186

HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 781-784FT-IR Study of Propylene Oxide Adsorption on Metal...

FT-IR Study of Propylene Oxide Adsorption on Metal Oxides

Abstract:

The adsorption of propylene oxide (PO) onto MgO, ZnO and Al₂O₃was investigated by using in situ-IR measurements. Detailed mechanisms for PO adsorption onto these metal oxides are proposed. It was found that the PO epoxide ring exhibits two opening tendencies, depending on the acid-base properties of the metal oxide. PO adsorbed onto MgO is preferentially opened at the O-C (1) bond. The epoxide ring provides two ways to open, at the O-C (1) or the O-C(2) bond on Al₂O₃. PO adsorbed onto ZnO showed no chemical adsorption on its surface.

You might also be interested in these eBooks

View Preview

Info:

Periodical:

Advanced Materials Research (Volumes 781-784)

Pages:

169-173

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.781-784.169

Citation:

Cite this paper

Online since:

September 2013

Authors:

Wen Yu Zhang*, Jing Guo Li, Feng Ma, Xiao Yong Yang

Keywords:

Adsorbed State, Al₂O₃, IR, MgO, Propylene Oxide, ZNO

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

Citation:

* - Corresponding Author

References

[1] W.Y. Dong, T.N. Gao, CN Patent 1033742C (1993).

Google Scholar

[2] Gregory, D.J. Westlake, US Patent 4440958 (1984).

Google Scholar

[3] P.A. Martin, T. William, C. Malama, US Patent 5110992 (1992).

Google Scholar

[4] W.J. Smith, F.C. Malherbe, US Patent 6291720B1 (2001).

Google Scholar

[5] H. Hattori, In: Proceedings of the Third International Symposium on Heterogeneous Catalysis and fine Chemicals, Poitiers, 1993, P. L19.

Google Scholar

[6] G. Zhang, H. Hattori, K. Tanabe, Appl. Catal. Vol. 36 (1988), p.98.

Google Scholar

[7] J.I. Di Cosimo, V.K. Díez, C.R. Apesteguía, Appl. Catal. Vol. 137 (1996), p.149.

Google Scholar

[8] A. Coma, S. Iborra, J. Primoo, F. Rey, Appl. Catal. Vol. 114 (1994), p.215.

Google Scholar

[9] A. Molar, I. Bucsi, M. Bartok, J. Catal. 129(1991)303.

Google Scholar

[10] W.C. Choi, J.S. Kim, T.H. Lee, S.I. Woo, Catal. Today Vol. 63 (2000), p.229.

Google Scholar

[11] Wenyu Zhang, Hui Wang, Wei Wei, Yuhan Sun, J. Mol. Catal. A: Chem, 2005, Vol 231(2004), p.83.

Google Scholar

[12] Muhua wang, Qingnian Dong, Wenyu Zhang, Wei Wei, Yuhan Sun, Chemical Journal of Chinese Universities (Gao Deng Xue Xiao Hua Xue Xue Bao)，Vol. 27(1), p.1.

Google Scholar