Structural Characterization of Serial Novel Star-Shaped Biodegradable Material Poly(lactic acid-co-melamine)

Abstract:

Using flame retardant melamine (MA) as a new aromatic core, biodegradable material poly (lactic acid-co-melamine) [P(LA-co-MA)] with different molar feed ratios are synthesized via direct melt copolycondensation. The structures of P(LA-co-MA) s are characterized by FT-IR, ¹H-NMR, ¹³C-NMR and GPC. The results indicate that MA moiety as the core is incorporated into the PLA backbone as expected, and the obtained products are copolymers indeed.

• Periodical: Advanced Materials Research (Volumes 781-784)
• Pages: 491-494
• DOI: https://doi.org/10.4028/www.scientific.net/AMR.781-784.491
• Online since: September 2013
• Authors: Guang Zhen Mo, Jin Feng Xiong, Pai Peng, Zhao Yang Wang
• Keywords: Biodegradable Material, Direct Melt Polycondensation (DMP), Melamine, Star-Shaped Poly(lactic acid) (SPLA), Structural Characterization

References

[1] S. Bourbigot and G. Fontaine: Polym. Chem. Vol. 1 (2010), p.1413.

[2] X. Wang, Y. Hu, L. Song, S.Y. Xuan, W.Y. Xing, Z.M. Bai and H.D. Lu: Ind. Eng. Chem. Res. Vol. 50 (2011), p.713.

[3] J.W. Gu, G.C. Zhang, S.L. Dong, Q.Y. Zhang and J. Kong: Surf. Coat. Technol. Vol. 201 (2007), p.7835.

[4] J.X. Feng, S.P. Su and J. Zhu: Polym. Adv. Technol. Vol. 22 (2011), p.1115.

[5] M.H. Feng, J.F. Xiong, Q.F. Wang and Z.Y. Wang: submitted to this meeting (2013).

[6] Z.Y. Wang and J.F. Xiong, Chinese Patent CN 102746497A. (2012).

[7] J.F. Xiong, S.H. Luo, Q.F. Wang, Z.Y. Wang and J. Qi: Des. Monomers Polym. Vol. 16 (2013), p.389.

[8] Z.Y. Wang, H. J. Zhao, Q.F. Wang, R.R. Ye and E.F. David: J. Appl. Polym. Sci. Vol. 117 (2010), p.1405.

[9] Z.Y. Wang, Y.F. Luo, R.R. Ye and X.M. Song: J. Polym. Res. Vol. 18 (2011), p.499.

[10] S.H. Luo, Z.Y. Wang, C.X. Mao and J.P. Huo: J. Polym. Res. Vol. 18 (2011), p. (2093).

[11] S.H. Luo, Q.F. Wang, J.F. Xiong and Z.Y. Wang: J. Polym. Res. Vol. 19 (2012), p.9962.

[12] Q.F. Wang, J.F. Xiong, M.L. Zhong and Z.Y. Wang: submitted to this meeting (2013).

[13] M. Purcell, J.F. Neault, H. Malonga, H. Arakawa, R. Carpentier and H.A. Tajmir-Riahi: Biochim. Biophys. Acta. Vol. 1548 (2001), p.129.

[14] H.S. Patel and V.C. Patel: Polym. Int. Vol. 52 (2003), p.304.

[15] J.F. Dai and B. Li: J. Appl. Polym. Sci. Vol. 116 (2010), p.2157.

[16] J.C. Wang and Y. Guo: J. Appl. Polym. Sci. Vol. 122 (2011), p.3474.

[17] F.Z. El-Ablack: E-J. Chem. Vol. 8 (2011), p.748.

[18] D.Y. Wang, Y.P. Song, L. Lin, X.L. Wang and Y.Z. Wang: Polymer Vol. 52 (2011), p.233.

[19] H.A. Orgueira, M. Bueno, J.L. Funes, J.A. Galbis and O. Varela: J. Polym. Sci. A: Polym. Chem. Vol. 36 (1998), p.2741.

DOI: 10.1002/(sici)1099-0518(19981115)36:15<2741::aid-pola10>3.0.co;2-e

[20] S. Jahromi, W. Gabriëlse and A. Braam: Polymer Vol. 44 (2003), p.25.

[21] A. Baraka, P.J. Hall and M.J. Heslop: React. Funct. Polym. Vol. 67 (2007), p.585.

[22] K. Siimer, T. Kaljuvee, T. Pehk and I. Lasn: J. Therm. Anal. Calorim. Vol. 99 (2010), p.755.

DOI: 10.1007/s10973-009-0617-z

[23] L.J. Zhang, F. Rakotondradany, A.J. Myles, H. Fenniri and T.J. Webster: Biomaterials Vol. 30 (2009), p.1309.