Structure and Properties of Cotton Grafted Using Trifluoroethyl Methacrylate via ATRP Method

Shi Wei Li; Tie Ling Xing; Zhan Xiong Li; Guo Qiang Chen

doi:10.4028/www.scientific.net/AMR.796.364

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HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 796Structure and Properties of Cotton Grafted Using...

Structure and Properties of Cotton Grafted Using Trifluoroethyl Methacrylate via ATRP Method

Abstract:

In this work, cotton was grafted with trifluoroethyl methacrylate (TFEMA) via atom transfer radical polymerization (ATRP) in water aqueous. The appearance of the cotton fabric was characterized with SEM, and SEM of the grafted cotton displayed significant difference from the ungrafted cotton. FT-IR indicated that TFEMA was successfully grafted onto surface of cotton fibers. Surface contact angle test and water repellency rating test showed that the water repellence of the modified cotton fabric were better than the ungrafted cotton fabric. Compared with the ungrafted cotton fabric, the whiteness, air permeability, breaking strength and elongation at break of the grafted cotton fabric decreased slightly. Grafted treatment led to efficient implantation of fluorine atoms on the surface of cotton fabric, this resulted in water repellence without altering the bulk properties of the cotton fabric.

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Periodical:

Advanced Materials Research (Volume 796)

Pages:

364-369

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.796.364

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Online since:

September 2013

Authors:

Shi Wei Li, Tie Ling Xing, Zhan Xiong Li, Guo Qiang Chen

Keywords:

Atom Transfer Radical Polymerization, Cotton Fabric, Structure Properties, TFEMA, Water Repellence

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