Synthesis and Crystal Structure of the Flexible Ligand Coordination Polymer [Co3(bpd)5.5(NCS)6(NH3)]n⋅2H2O(bpd= 1,4-bis (4-pyridyl)-2,3-diaza-1,3-butadiene)

Yu Qi Liu; Yong Yang; Rui Yang; Xiao Jun Xu

doi:10.4028/www.scientific.net/AMR.803.80

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Synthesis and Crystal Structure of the Flexible Ligand Coordination Polymer [Co₃(bpd)_5.5(NCS)₆(NH₃)]_n⋅2H₂O(bpd= 1,4-bis (4-pyridyl)-2,3-diaza-1,3-butadiene)
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HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 803Synthesis and Crystal Structure of the Flexible...

Synthesis and Crystal Structure of the Flexible Ligand Coordination Polymer [Co₃(bpd)_5.5(NCS)₆(NH₃)]_n⋅2H₂O(bpd= 1,4-bis (4-pyridyl)-2,3-diaza-1,3-butadiene)

Abstract:

A novel metalorganic coordination polymer, namely [Co₃(bpd)_5.5(NCS)₆(NH₃)]_n2H₂O (1) (bpd=1,4-bis (4-pyridyl)-2,3-diaza-1,3-butadiene), has been synthesized and characterized by elemental analyses, infrared spectroscopy, and single-crystal X-ray diffraction. Compound 1 presents 2D[3,4,-connected 3-nodal net with the point symbol (4²68²10)(4⁴6²)(8²10). In addition, four identical 2D single nets is interlocked with each other in parallel, thus directly leading to the formation of a polycatenated layer (2D2D).

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Periodical:

Advanced Materials Research (Volume 803)

Pages:

80-84

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.803.80

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Online since:

September 2013

Authors:

Yu Qi Liu, Yong Yang, Rui Yang, Xiao Jun Xu

Keywords:

1,4-Bis(4-Pyridyl)-2,3-Diaza-1,3-Butadiene, Coordination Polymer, Synthesis, Topology

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