Magnetic Nanoparticles Supported Binuclear Manganese(II) Complex via Covalent Interaction: A Highly Efficient and Reusable Catalyst for the Epoxidation of Cyclohexene

Massomeh Ghorbanloo; Roghayeh Tarasi

doi:10.4028/www.scientific.net/AMR.829.416

Paper Titles

The Effect of Cu Doping on LPG Response of the SnO₂ Nanostructure Layer
p.391

Effect of Rapid Thermal Annealing on the Structural and Magnetic Properties of Nanostructured FePt Thin Films
p.396

Effect of Introducing Free Gaseous Radicals of Trichlorosilane and Ammonia Precursors on Growth and Characteristics of LPCVD a-SiNx Ultra Thin Films
p.401

Effect of Pulse Electrodeposition on Properties of Nanocrystalline Nickel Coatings
p.410

Magnetic Nanoparticles Supported Binuclear Manganese(II) Complex via Covalent Interaction: A Highly Efficient and Reusable Catalyst for the Epoxidation of Cyclohexene
p.416

Direct Growth of ZnO Nanorods on Zinc Substrate via Hydrothermal Method
p.421

Challenges Regarding to Usage of Nanostructured Materials in Contemporary Building Construction
p.426

Effects of Anodic Oxidation in Ethylene Glycol Based Electrolyte on the Corrosion Resistance and Biocompatibility of NiTi Shape Memory Alloy
p.431

Phosphate-Free Protective Nanoceramic Coatings for Galvanized Steel Sheet with H₂O₂ Additive
p.436

HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 829Magnetic Nanoparticles Supported Binuclear...

Magnetic Nanoparticles Supported Binuclear Manganese(II) Complex via Covalent Interaction: A Highly Efficient and Reusable Catalyst for the Epoxidation of Cyclohexene

Abstract:

In the present work, the highly efficient epoxidation of cyclohexene catalyzed by Fe₃O₄@SiO₂/([Mn₂L(HL)(H₂O)₄], is reported. First, the Fe₃O₄@SiO₂ nanoparticles were modified with (3-chloropropyl)-trimethoxysilane (CPTMS) group and then [Mn₂(HL)₂(H₂O)₄] was attached to the support via covalent linkages. The prepared catalyst was characterized by spectroscopic studies and chemical analyses. This catalytic system serves as catalyst for the oxidation of cyclohexene to cyclohexene epoxide and 2-cyclohexene-1-ol using H₂O₂ as an oxidant. Thus, this catalytic system shows high activity and selectivity toward cyclohexene epoxide. Also activity of the immobilized catalyst remains nearly unchanged after five cycles, that it is truly heterogeneous.

You might also be interested in these eBooks

Ultrafine Grained and Nano-Structured Materials IV

View Preview

Info:

Periodical:

Advanced Materials Research (Volume 829)

Pages:

416-420

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.829.416

Citation:

Cite this paper

Online since:

November 2013

Authors:

Massomeh Ghorbanloo, Roghayeh Tarasi

Keywords:

Catalyst, Epoxidation, Magnetic, Nanoparticle, Reusable

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

Citation:

References

[1] Q.H. Xia, H.Q. Ge, C.P. Ye, Z.M. Liu, K.X. Su, Advances in homogeneous and heterogeneous catalytic asymmetric epoxidation, Chem. Rev. 105 (2005) 1603–1662.

DOI: 10.1021/cr0406458

Google Scholar

[2] B. Qi, X. -H. Lu, D. Zhou, Q. -H. Xia, Z. -R. Tang, S. -Y. Fang, T. Pang, Y. -L. Dong, Catalytic epoxidation of alkenes with 30% H2O2 over Mn2+-exchanged zeolites, J. Mol. Catal. A 322 (2010) 73–79.

DOI: 10.1016/j.molcata.2010.02.019

Google Scholar

[3] M. Ghorbanloo, M. Jaworska, P. Paluch, G.D. Li, L. Zhou, Synthesis, characterization, and catalytic activity for thioanisole oxidation of homogeneous and heterogeneous binuclear manganese(II) complexes with amino acid-based ligands, J. Transit Met. Chem. 38 (2013).

DOI: 10.1007/s11243-013-9718-4

Google Scholar

[4] J. Wang, S. Zheng, Y. Shao, J. Liu, Z. Xu, D. Zhu, Amino-functionalized Fe3O4@SiO2 core–shell magnetic nanomaterial as a novel adsorbent for aqueous heavy metals removal, J. Colloid Interface Sci. 349 (2010) 293–299.

DOI: 10.1016/j.jcis.2010.05.010

Google Scholar

[5] M. Shokouhimehr, Y. Piao, J. Kim, Y. Jang, T. Hyeon, A Magnetically Recyclable nanocomposite Catalyst for Olefin Epoxidation, Angew. Chem., Int. Ed. 46 (2007) 7039–7043.

DOI: 10.1002/anie.200702386

Google Scholar

[6] A. Pordea, D. Mathis, T.R. Ward, Incorporation of biotinylated manganese-salen complexes into streptavidin: New artificial metalloenzymes for enantioselective sulfoxidation, J. Organomet. Chem. 649 (2009) 930–936.

DOI: 10.1016/j.jorganchem.2008.11.023

Google Scholar

[7] D. Chatterjee, A. Mitra, Olefin epoxidation catalysed by Schiff-base complexes of Mn and Ni in heterogenised-homogeneous systems, J. Mol. Catal. A: Chem 144 (1999) 363–367.

DOI: 10.1016/s1381-1169(99)00093-x

Google Scholar