Solvothermal Synthesis, Structure, Fluorescence and Magnetism Properties of a Novel 3D Metal-Organic Framework Based on Tetranuclear Copper Secondary Building Units

Abstract:

A novel 3D metal-organic framework based on tetranuclear copper Secondary Building Units, [Cu₂(μ₃-OH)(4-oip)(DMF)]·DMF·2H₂O (JUC-76) (4-oip = 4-hydroxyisophthalic, DMF = N,N-dimethylformamide, and JUC = Jilin University China), has been synthesized under solvothermal conditions. It crystallizes in monoclinic symmetry with space group P2₁/n. JUC-76 possesses a three-dimensional network with one-dimensional rhombic channels of approximately 13.6 × 8.5 Ų along the [100] direction. The resulting structure of JUC-76 is a distorted rutile topology with one 3-connected organic node and one 6-connected inorganic node. And its Schläfli symbol is (4·6²)₂(4²·6¹⁰·8³). In addition, JUC-76 exhibits fluorescence emission at 446 nm, and a dominant anti-ferromagnetic interaction between the Cu (II) ions.

• Periodical: Advanced Materials Research (Volumes 834-836)
• Pages: 543-549
• DOI: https://doi.org/10.4028/www.scientific.net/AMR.834-836.543
• Online since: October 2013
• Authors: Lei Wu*, Ming Xue, Gérald Chaplais, Guang Shan Zhu, Shi Lun Qiu, Angélique Simon-Masseron, Joël Patarin
• Keywords: Fluorescence, Magnetism, MOF, Topology

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