Nanoreinforcement of Pectin Film to Enhance its Functional Packaging Properties by Incorporating ZnO Nanoparticles

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The main objective of this study was to enhance functional packaging properties of pectin film by using zinc oxide nanoparticles (ZnO-NPs) as nanoreinforcing agent. Pectin/ZnO bio-nanocomposite films were fabricated at 4 levels of ZnO-NPs, i.e., 0.5, 1.0, 2.0 and 5.0% (w/w). The effects of ZnO-NPs incorporation on improving the mechanical properties and water resistance of the films were investigated. ZnO-NPs were successfully incorporated into pectin films by nanodispersion technique followed by casting method. The presence of ZnO-NPs inside pectin films was observed clearly by SEM. The improvement in tensile strength could be achieved with ZnO-NPs incorporation without obvious loss in elasticity. Potential antimicrobial activity of pectin-ZnO nanocomposite films was proved in the absence of mold after exposing them at 97% RH and room temperature for 14 days, whereas the growth of mold had been observed in pure pectin film after 3 days of exposure. In terms of film transparency, the significant change in film opacity was only found in the film prepared with 5% of ZnO. Results suggested that it would be favorable to prepare pectin/ZnO nanocomposite film by using ZnO-NPs at the amount of 2% (w/w) in the future work.

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451-456

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December 2013

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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[1] G. Elegir, A. Kindl, P. Sadocco, M. Orlandi. Development of antimicrobial cellulose packaging through laccase-mediated grafting of phenolic compounds. Enzyme Microb Tech 43 (2008) 84–92.

DOI: 10.1016/j.enzmictec.2007.10.003

Google Scholar

[2] J. Vartiainen, T. Tammelin, J. Pere, U. Tapper, A. Harlin. Biohybrid barrier films from fluidized pectin and nanoclay. Carbohydr Polym. 82 (2010) 989–996.

DOI: 10.1016/j.carbpol.2010.06.031

Google Scholar

[3] M.L. Fishman D.R. Coffin, C.I. Onwulata, R.P. Konstance. Extrusion of pectin and glycerol with various combinations of orange albedo and starch. Carbohydr Polym 57 (2004) 401–403.

DOI: 10.1016/j.carbpol.2004.05.014

Google Scholar

[4] M.L. Fishman, D.R. Coffin. Mechanical, microstructural and solubility properties of pectin/poly(vinyl alcohol) blends. Carbohydr Polym 35 (1998) 195–203.

DOI: 10.1016/s0144-8617(97)00245-2

Google Scholar

[5] L. Mariniello, P. Di Pierro, C. Esposito, A. Sorrentino, P. Masi, R. Porta. Prepa ration and mechanical properties of edible pectin–soy flour films obtained in the absence or presence of transglutaminase. J Biotechnol 102 (2003) 191–8.

DOI: 10.1016/s0168-1656(03)00025-7

Google Scholar

[6] C. Jo, H. Kang, N.Y. Lee, J.H. Kwon, M.W. Byun. Pectin- and gelatin-based film: effect of gamma irradiation on the mechanical properties and biodegrada- tion. Radiat Phys Chem 72 (2005) 745–50.

DOI: 10.1016/j.radphyschem.2004.05.045

Google Scholar

[7] K. Ofori-Kwakye, J.T. Fell. Leaching of pectin from mixed films containing pectin, chitosan and HPMC intended for biphasic drug delivery: Int J Pharm 250 (2003) 251–7.

DOI: 10.1016/s0378-5173(02)00546-x

Google Scholar

[8] G.S. Macleod, J.T. Fell, J.H. Collett. Studies on the physical properties of mixed pectin/ethylcellulose films intended for colonic drug deliver y. Int J Pharm 157 (1997) 53–60.

DOI: 10.1016/s0378-5173(97)00216-0

Google Scholar

[9] A. Sorrentino, G. Gorrasi, V. Vittoria. Potential perspectives of bio- nanocomposites for food packaging applications. Trends Food Sci Technol 18 (2007) 84-95.

DOI: 10.1016/j.tifs.2006.09.004

Google Scholar

[10] A. Arora, G.W. Padua. Review: Nanocomposites in food packaging. J. Food Sci, 75 (2010) 43–48.

Google Scholar

[11] L. Shi, S. Gunasekaran. Preparation of Pectin-ZnO nanocomposite. Nanoscale Res Let. 3 (2008) 491-495.

Google Scholar

[12] L. He, Y. Liu, A. Mustapha, M. Lin. Antifungal activity of zinc oxide nanoparticles against Botrytis cinerea and Penicillium expansum. Microbiol Res., 166 (2011) 207-215.

DOI: 10.1016/j.micres.2010.03.003

Google Scholar

[13] L. Zhang, Y. Jiang, Y. Ding, M. Povey, D. York. Investigation into the antibacterial behavior of suspensions of ZnO nanoparticles (ZnO nanofluids). J Nanoparticle Res. 9 (2007) 479-489.

DOI: 10.1007/s11051-006-9150-1

Google Scholar

[14] L.E. Shi, X.J. Fang, Z.L. Zhang, T. Zhou, D. Jiang, H.H. Wu, Z.X. Tang. Preparation of nano-ZnO using sonication method and its antibacterial characteristics. Int. J. Food Sci Tech., 47 (2012) 1866-1871.

DOI: 10.1111/j.1365-2621.2012.03043.x

Google Scholar