Preparation of Ni Loaded on Zeolite and its Application for Conversion of Glycerol to Hydrogen

Article Preview

Abstract:

Glycerol is the main by-product of biodiesel production and during the trans-esterification reaction, about 10 wt % of glycerol is produced. In this study, different amount of Ni was loaded on HZSM-5 and tested for the conversion of glycerol to hydrogen. The studies were also conducted at different reactor temperature of 450, 500, 550, 600 and 650°C respectively. The structural characterization of the catalyst was carried out using the XRD. It was found that, the addition of 15 wt % of nickel loaded on HZSM-5 shows the highest glycerol conversion of 98.54%. In addition, it produces the highest yield of hydrogen gas operated at reactor temperature of 600°C.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

457-461

Citation:

Online since:

December 2013

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Z. X. Wang, J. Zhugea, H. Fanga, B.A. Prior, Glycerol Production by Microbial Fermentation: A Review, Biotechnology Advances 19 (2001) 201–223.

DOI: 10.1016/s0734-9750(01)00060-x

Google Scholar

[2] B.C.R. Ewan, and R.W.K. Allen, A Figure of Merit Assessment of the Routes to Hydrogen, International Journal Hydrogen Energy 30(8) (2005) 809–819.

DOI: 10.1016/j.ijhydene.2005.02.003

Google Scholar

[3] S. Adhikari, S.D. Fernando, Agus Haryanto, Hydrogen production from glycerol: An update. Energy Conversion and Management 50 (2009) 2600–2604.

DOI: 10.1016/j.enconman.2009.06.011

Google Scholar

[4] S. Adhikari, S.D. Fernando, Agus Haryanto, Hydrogen Production from Glycerin by Steam Reforming over Nickel Catalysts, Renewable Energy 33 (2008) 1097–1100.

DOI: 10.1016/j.renene.2007.09.005

Google Scholar

[5] A. Iriondo V.L. Barrio, J.F. Cambra P.L. Anas M.B. Guemez, R.M. Navarro, Influence of La2O3 Modified Support and Ni and Pt Active Phases on Glycerol Steam Reforming to Produce Hydrogen, Catalysis Communications 10 (2009) 1275-1278.

DOI: 10.1016/j.catcom.2009.02.004

Google Scholar

[6] J.S. Galen, A.D. Mohanprasad, J.D. Eric, J.M. Pratik, J.G. Michael, Transesterification of Soybean Oil with Zeolite and Metal Catalysts, Applied Catalysis A: General 257 (2004) 213–223.

DOI: 10.1016/j.apcata.2003.07.010

Google Scholar

[7] S. Freni, S. Cavallaro, N. Mondello, L. Spadaro, F. Frusteri, Production of Hydrogen for MC Fuel Cell by Steam Reforming of Ethanol over MgO Supported Ni and CO Catalysts, Catalysis Communications 4 (2003) 259–268.

DOI: 10.1016/s1566-7367(03)00051-7

Google Scholar

[8] N. Shi, L. Qi-ying, Ting Jiang, M. Long-long, Qi Zhang, Xing-hua Zhang, Hydrodeoxygenation of Vegetable Oils to Liquid Alkane Fuels over Ni/HZSM-5 Catalysts: Methyl Hexadecanoate as the Model Compound. Catalysis Communications 20 (2012) 80–84.

DOI: 10.1016/j.catcom.2012.01.007

Google Scholar

[9] C. Lidong, W. Xiangsheng, G. Hongchen, G. Xinwen, W. Yanan, L. Hai'ou, L. Guimin, Hydroconversion of N-Octane Over Nanoscale HZSM-5 Zeolites Promoted By 12-Molybdophosphoric Acid and Ni, Catalysis Communications 8 (2007) 416–423.

DOI: 10.1016/j.catcom.2006.06.034

Google Scholar