Research in Non-Isothermal Crystallization Kinetics of LDPE Composite Films

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Abstract:

By means of melt blending process in a co-rotating twin screw extruder and blow molding , the low density polyethylene (LDPE)/thermoplastic elastomer(TPE) mixed membranes and LDPE/inorganic particles composite membrane were prepared. by differential scanning calorimetry(DSC) to study the non-isothermal crystallization kinetics of the LDPE composite system by differential scanning calorimetry (DSC).Use modified Jeziorny method to process the data ,the results shows that ZMS, SiO2, EVA and EMAA all play a role of heterogeneous nucleation and the crystallization rate of LDPE has been increased,especially the ZMS/LDPE composite system which heterogeneous nucleation is more obvious and crystallization rate is faster.

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46-49

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November 2013

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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[1] A. Jeziorny. Polymer. 19(1978), p.1142.

Google Scholar

[2] Feio G, Conen-Addad JP. NMR approach to the kinetics of polymer crystallization. cis- 1, 4 -Polybutadiene[J]. Journal of Polymer Science, Part B: Polymer Physics, 1988, 26(2): 389-412.

DOI: 10.1002/polb.1988.090260213

Google Scholar

[3] Cheng Stephen Z D. Kinetics of mesophase transitions in thermotropic copolyesters. 1. Calorimetric study [J]. Macromolecules, 1988, 21(8): 2475-2484.

DOI: 10.1021/ma00186a029

Google Scholar

[4] Kim S P, Kim S C. Crystallization kinetics of poly(ethylene terephthalate). Part I: Kinetic equation with variable growth rate[J]. Polym Eng Sci, 1991, 31(2): 110-115.

DOI: 10.1002/pen.760310209

Google Scholar

[5] Hsiao B. Some comments on modeling of two-stage crystallization kinetics[J]. J Polym Sci, Part B: Polymer Physics, 1993, 31(2): 237-240.

DOI: 10.1002/polb.1993.090310215

Google Scholar

[6] Eder G, Janeschitz-Kregl, Liedauer S. Crystallization processes in quiescent and moving polymer melts under heat transfer conditions[J]. Prog Polym Sci, 1990, 15: 629-634.

DOI: 10.1016/0079-6700(90)90008-o

Google Scholar

[7] Ziabicki A. Crystallization of polymer in variable external condition. part1[J]. Coll Polym Sci, 1996, 274: 209-217.

Google Scholar

[8] OTTANI S, PORTER R S. Calorimetric investigation on high molecular weight polyethylene reactor powders[J]. J Polym Sci, Part B: Polym Phys, 1991, 29: 1179-1188.

DOI: 10.1002/polb.1991.090291002

Google Scholar