Preparation and Stability Studies of a Desulfurizer Loaded on Porous Silica Gel

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Abstract:

A novel ionic liquid 1,1,3,3-tetramethylguanidinium lactate (TMGL) has been prepared. And the stability of ionic liquid was determined at different temperatures and pressures, which shows extremely low vapor pressure and high thermal stability. TMGL was immobilized by adjusting the feed ratio (TMGL/SiO2) and particle size, the concentration of 0.90% sulfur dioxide gas passed into a certain amount of the loaded ionic liquid TMGL-SiO2, quickly reduced to less than 0.05%, the concentration was measured by a BRUKER Infra-red Spectrometer. This ionic liquid has potential applications in flue gas desulphuration (FGD).

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92-95

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January 2014

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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[1] W. Z. Wu, B. X. Han, H. X. Gao, et al. Desulfurization of flue gas: SO2 absorption by an ionic liquid [J]. Angewandte Chemie-International Edition, 2004, 43(18): 2415-2417.

DOI: 10.1002/anie.200353437

Google Scholar

[2] Y. Y. Jiang, Z. Zhou, Z. Jiao, et al. SO2 gas separation using supported ionic liquid membranes [J]. Journal of Physical Chemistry B, 2007, 111(19): 5058-5061.

DOI: 10.1021/jp071742i

Google Scholar

[3] X. L. Yuan, S. J. Zhang and X. M. Lu. Hydroxyl ammonium ionic liquids: synthesis, Properties, and solubility of SO2 [J]. Journal of Chemical and Engineering Data, 2007, 52(2): 596-599.

DOI: 10.1021/je060479w

Google Scholar

[4] J. Huang, A. Riisager, P. Wasserscheid, et al. Reversible physical absorption of SO2 by ionic liquids [J]. Chemical Communications, 2006, 38: 4027-4029.

DOI: 10.1039/b609714f

Google Scholar

[5] D. An, L. B. Wu, B. G. Li, et al. Synthesis and SO2 absorption/desorption propertie of poly(1, 1, 3, 3-tetramethylguanidineacrylate)[J]. Macromolecules, 2007, 40(9): 3388-3393.

Google Scholar

[6] L. B. Wu, D. An, J. Dong, et al. Preparation and SO2 absorption/desorption properties of crosslinked poly(1, 1, 3, 3-tetramethylguanidine acrylate) porous [J]. Macromolecular Rapid Communications, 2006, 27(22): 1949-(1954).

DOI: 10.1002/marc.200600563

Google Scholar

[7] Z. M. Zhang, L. B. Wu, J. Dong, et al. Preparation and SO2 sorption/desorption Behavior of an ionic liquid supported on porous silica particles [J]. Ind. Eng. Chem. Res., 2009, 48(4): 2142-2148.

DOI: 10.1021/ie801165u

Google Scholar