Novel Post-Treatment Process by La3+ Modification to TiO2 Photoanode with Enhanced Performance for DSSCs

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Abstract:

Photoanodes are critical parts of dye-sensitized solar cells (DSSCs), which are composited of TCO (transparent conductive oxide) glasses and nanocrystalline semiconductor film deposited on them. Post-treatment of porous TiO2 film after sintering for the first time was important for the enhancement of the performance of DSSCs. A novel method to modify the surface of TiO2 film was investigated in our work. Photoanodes of DSSCs were treated with the isopropanol solution containing 0.05mol/L La (NO3)3. After the post-treatment, there was an obvious increase of the overall performance of DSSCs. The photoelectric conversion efficiency (PCE) reached 9.33%, with a raise of 3.3%, compared with the traditional TiCl4 thermal treating method at 70°C for 40min.

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Advanced Materials Research (Volumes 860-863)

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219-222

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December 2013

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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