Preparation of High Voltage Spinel LiNi0.5Mn1.5O4 Cathode Material Using Polymer-Assisted Co-Precipitation Procedure

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Abstract:

Cathode material LiNi0.5Mn1.5O4 was synthesized via oxalate co-precipitation process using LiCl,NiCl2·6H2O and MnCl2·4H2O as raw materials, oxalate as precipitant. The effects of calcining temperature and polymer-assisted during the synthetic process on the performance of the products were analyzed. When calcining at 700°C for 10h and with assistance of polyacrylic acid as dispersive, the synthesized product had cubic spinel structure, uniform particle size and the aggregations of particle was reduced.

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Advanced Materials Research (Volumes 860-863)

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885-889

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December 2013

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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[1] Liu GQ, Wen L, Liu YM. J Solid State Electrochem Vol. 14(2010), p.2191.

Google Scholar

[2] Ohzuku T, Takeda S, Iwanaga M. J Power Sources Vol. 81(1999), p.90.

Google Scholar

[3] Q.M. Zhong, A. Bonakdarpour, M.J. Zhang, Y. Gao, J.R. Journal of the Electrochemical Society Vol. 144 (1997), p.205.

Google Scholar

[4] H. Duncan, D. Duguay, Y. Abu-Lebdeh, I.J. Davidson. Journal of the Electrochemical Society Vol. 158 (5) (2011), pA537.

Google Scholar

[5] Lee YS, Sun YK, Ota S, Miyashita T, Yoshio M. Electrochem Commun Vol. 4 (2002), p.989.

Google Scholar

[6] Fan Y, Wang J, Ye X, Zhang J. Mater Chem Phys Vol. 103 (2007), p.19.

Google Scholar

[7] D. Li, A. Ito, K. Kobayakawa, H. Noguchi, Y. Sato, Electrochemical characteristics of LiNi0. 5Mn1. 5O4 prepared by spray drying and post-annealing, Electrochimica Acta Vol. 52 (2007), p.1919.

DOI: 10.1016/j.electacta.2006.07.056

Google Scholar

[8] M. Kunduraci, J.F. Al-Shara, G.G. Amatucci. Journal of the Electrochemical Society Vol. 153 (2006), pA1345.

Google Scholar

[9] X. Huang, Q. Zhang, J. Gan, H. Chang, Y. Yang Vol. 158 (2) (2011), pA139.

Google Scholar

[10] M. Kunduraci, J.F. Al-Sharab, G.G. Amatucci, Chem. Mater. Vol. 18 (2006), p.3585.

Google Scholar

[11] H. Fang, L. Li, G. Li, J. Power Sources Vol. 167 (2007), p.223.

Google Scholar

[12] Gong K, Yu P, Su L, Xiong S, Mao L. J Phys Chem C Vol. 111(2007), p.1882.

Google Scholar

[13] Yi-Chun Jin, Jenq-Gong Duh. Materials Letters Vol. 93(2013), p.77.

Google Scholar