Crystallization Behavior and Infrared Radiation Properties of Copper Ferrite-Doped MgO-Al2O3-SiO2 Ceramics

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Abstract:

MgO-Al2O3-SiO2 ceramics were recently explored as infrared radiance materials to provide an environmental friendly energy candidate for industrial heating and drying. Cu ferrite was selected to dope MgO-Al2O3-SiO2 ceramics, forming a series of composite ceramics via solid-state reaction method to enhance the infrared radiation properties. The phase identification and morphologies of the samples were characterized by X-ray diffraction (XRD) and scanning electron microscope (SEM) techniques. The infrared emissivity was examined by Fourier transform infrared (FTIR) spectrometer. The results showed that an improvement of infrared radiation properties can be achieved by doping Cu ferrite in MgO-Al2O3-SiO2 ceramics. With increasing the dopant content from 0 wt % to 10.0 wt %, the crystallization behavior changed accordingly. A positive correlation was found between the infrared emissivity and the lattice strain. The highest infrared emissivity (0.91±0.01) was obtained after sintering at 1150 °C for 2 h with Cu ferrite content was 7.5 wt %, in which the maximum lattice strain (0.282 %) occurred. MgO-Al2O3-SiO2 ceramics doped with Cu ferrite have potential for the application of infrared heating and drying fields.

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Advanced Materials Research (Volumes 860-863)

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881-884

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December 2013

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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