Studies on the Properties of Banana Fibers-Reinforced Thermoplastic Cassava Starch Composites: Preliminary Results

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Banana fibers received four treatments, namely squeezing, alkali and hydrogen peroxide treatment, washing with water, and drying. Thermoplastic starch composites was prepared with glycerol as the plasticizer, banana fiber as reinforcement and thermoplastic cassava starch as matrix. The banana fiber could increase processing torque highly, while the effects of fiber contents on peak torque at 3min was so obvious. X-ray diffractograms illustrated that with increasing fiber content, cellulose crystallinity at 22.5° gradually got stronger but starch crystallinity at 20° almost didn’t. SEM micrographs showed good dispersion and adhesion between starch and fiber. Studies in the dependence of mechanical properties of reinforced TPS on the contents of fiber that with increasing fiber content from 0 to 20phr, the initial tensile strength was trebled up to 14.46 MPa, while the elongation at break was reduced from 68 to 13%. TG mass loss curves showed that thermal stability of this composites had great improved under 500°C.

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Advanced Materials Research (Volumes 87-88)

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439-444

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December 2009

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© 2010 Trans Tech Publications Ltd. All Rights Reserved

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[1] P. P. Klemchuk. Degradable plastics: a critical review, Polymer Degradation and Stability. Vol. 27(1990), p.183.

DOI: 10.1016/0141-3910(90)90108-j

Google Scholar

[2] A. A. S. Curvelo, A. J. F. Carvalho, & J. A. M. Agnelli. Thermoplastic starch- cellulosic fibers composites: preliminary results. Carbohydrate Polymer, Vol. 45(2001), p.183.

DOI: 10.1016/s0144-8617(00)00314-3

Google Scholar

[3] A. S. Herrmann, J. Nickel, & U. Riedel. Construction materials based upon biologically renewable resources-from components to finished parts. Polymer Degradation and Stability, Vol. 59(1998), p.251.

DOI: 10.1016/s0141-3910(97)00169-9

Google Scholar

[4] P. M. Forssell, J. M. Mikkila¨, & G. K. Moates. Phase and glass transition behaviour of concentrated barley starch-glycerol-water mixtures: a model for thermoplastic starch. Carbohydrate Polymers, Vol. 34(1997), p.275.

DOI: 10.1016/s0144-8617(97)00133-1

Google Scholar

[5] S. H. D. Hulleman, F. H. P. Janssen, & H. Feil. The role of water during plasticization of native starches. Polymer, Vol. 39 (1998), p. (2043).

DOI: 10.1016/s0032-3861(97)00301-7

Google Scholar

[6] L. Averous, N. Fauconnier, & L. Moro. Blends of thermoplastic starch and polyester-amide: processing and properties. Journal of Applied Polymer Science, Vol. 76(2000).

DOI: 10.1002/(sici)1097-4628(20000516)76:7<1117::aid-app16>3.0.co;2-w

Google Scholar

[7] D. Demirgöz, C. Elvira, & J. F. Mano. Chemical modification of starch based biodegradable polymeric blends: effects on water uptake, degradation behaviour and mechanical properties. Polymer Degradation and Stability, Vol. 70(2000), p.161.

DOI: 10.1016/s0141-3910(00)00102-6

Google Scholar

[8] A. Dufresne, & M. R. Vignon. Improvement of starch film performance using cellulose microfibers. Macromolecules, Vol. 31 (1998), p.2693.

DOI: 10.1021/ma971532b

Google Scholar

[9] M. Wollerdorfer, & H. Bader. Influence of natural fibres on the mechanical properties of biodegradable polymers. Industrial Crops and Products, Vol. 8(1998), p.105.

DOI: 10.1016/s0926-6690(97)10015-2

Google Scholar

[10] U. Funke, W. Bergthaller, & M. G. Lindhauer. Processing and characterization of biodegradable products based on starch. Polymer Degradation and Stability, Vol. 59(1998), p.293.

DOI: 10.1016/s0141-3910(97)00163-8

Google Scholar

[11] A. Dufresne, D. Dupeyre, & M. R. Vignon. Cellulose microfibrils from potato tuber cells: Processing and characterization of starchcellulose microfibril composites. Journal of Applied Polymer Science, Vol. 76(2000), p. (2080).

DOI: 10.1002/(sici)1097-4628(20000628)76:14<2080::aid-app12>3.0.co;2-u

Google Scholar

[12] X.F. Ma, J.G. Yu, J.F. Kennedy. Studies on the properties of natural fibers reinforced thermoplastic starch composites. Carbohydrate Polymers, Vol. 62(2005), p.19.

DOI: 10.1016/j.carbpol.2005.07.015

Google Scholar

[13] J.Y. Pang, X.Z. Mo, & Y. Liang. Modification of banana fiber and properties of epoxy composites, Technology & Development of Chemical Industry, Vol. 37(2008), p.6.

Google Scholar

[14] K. Vijay, & H. K. Sanjeev. Effect of compressional force on the crystallinity of directly compressible cellulose excipients. International Journal of Pharmaceutics, Vol. 177(1999), p.173.

DOI: 10.1016/s0378-5173(98)00340-8

Google Scholar

[15] A. Amash, & P. Zugenmaier. Morphology and properties of isotropic and oriented samples of cellulose fibre-polypropylene composites. Polymer, Vol. 41(2000), p.1589.

DOI: 10.1016/s0032-3861(99)00273-6

Google Scholar