A Green Procedure for the Ionic Liquid Catalyzed Oxidation of Benzylic Alcohols to Aldehydes or Ketones in Aqueous Media

Guo Feng Zhang; Xiu Jie Ji; Bo Wen Cheng; Jun Song; Fei Lu; Ran Ran Fu; Jie Ru Huang; Peng He Su; Xiao Rong Gou; Lu Yang Chen; Chao Liu

doi:10.4028/www.scientific.net/AMR.873.567

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HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 873A Green Procedure for the Ionic Liquid Catalyzed...

A Green Procedure for the Ionic Liquid Catalyzed Oxidation of Benzylic Alcohols to Aldehydes or Ketones in Aqueous Media

Abstract:

A green oxidation of benzylic alcohols to the corresponding aldehydes or ketones was achieved in aqueous media using ionic liquid/H₂O₂/HCl catalytic oxidation system. The procedure is mild, environment-friendly and simple. Ionic liquids can be successfully recovered and reused for the oxidation of the same (different) substance. The directing effect of the ionic liquid is supported by the good selectivities and yields. These reactions demonstrate the catalytic oxidation and phase transfer function of the ionic liquid is stronger than that without ionic liquid.

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Periodical:

Advanced Materials Research (Volume 873)

Pages:

567-570

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.873.567

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Online since:

December 2013

Authors:

Guo Feng Zhang*, Xiu Jie Ji, Bo Wen Cheng, Jun Song, Fei Lu, Ran Ran Fu, Jie Ru Huang, Peng He Su, Xiao Rong Gou, Lu Yang Chen, Chao Liu

Keywords:

Alcohols, Aldehydes, Ionic Liquid (IL), Ketones, Oxidation

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