Effect of Fluorine-Containing Surfactant on Fluorinated Acrylate Emulsion Polymerization and the Properties of the Latex Film

Abstract:

Fluorine-containing acrylate monomer modified acrylate hybrid latex particles were synthesized by seeded emulsion polymerization with methyl methacrylate (MMA), butyl acrylate (BA), methacrylic acid (MAA), hydroxyethyl methacrylate (HEMA), and trifluoroethyl methacrylate (TFMA) in the presence of three kinds of surfactant mixture conditions, respectively. The effect of different surfactant mixtures on properties of fluorinated acrylate latex and film were investigated. Chemical composition and morphology of the resultant hybrid latex particles were respectively characterized by Fourier transform infrared (FT-IR) spectroscopy and transmission electron microscopy (TEM). The addition of a small amount fluorine-containing surfactant leads to an increase of the monomer conversion and improvement of thermal stability of the latex. The average particle size of the latex prepared in the presence of OP-10/Le-180s/CO-436/Le-003 surfactant mixture was uniform and the particle distribution was narrow; thermogravimetric analysis (TGA) indicated the hybrid latex possessed good thermal stability, and the result also revealed the latex exhibited good dilution, refrigeration as well as Ca²⁺ stability.

• Periodical: Advanced Materials Research (Volumes 875-877)
• Pages: 130-134
• DOI: https://doi.org/10.4028/www.scientific.net/AMR.875-877.130
• Online since: February 2014
• Authors: Wei Yang, Yi Chi Chen, Xiao Qun Wang, Dong Xiao Han, Li Qun Zhu
• Keywords: Film Property, Fluorinated Acrylic Latex, Fluorine-Containing Surfactant, Latex Stability, Seeded Emulsion Polymerization

References

[1] V.C. Malshe, S. Elango, S.S. Bhagwat, S.S. Maghrabi, Progress in Organic Coatings, 53 (2005) 212-216.

DOI: 10.1016/j.porgcoat.2005.03.004

[2] M.A. Massimo Lazzari, Valter Castelvetro, Oscar Chiantore, Polymer Degradation and Stability, 79 (2003) 345-351.

[3] T. Narita, Journal of Polymer Science Part A: Polymer Chemistry, 42 (2004) 4101-4125.

[4] J. Gao, X. Wang, Y. Wei, W. Yang, Journal of Fluorine Chemistry, 127 (2006) 282-286.

[5] J. -W. Ha, I.J. Park, D. -K. Kim, J. -H. Kim, S. -B. Lee, Surface Science, 532 (2003) 328-333.

[6] J. -Q. Huang, W. -D. Meng, F. -L. Qing, Journal of Fluorine Chemistry, 128 (2007) 1469-1477.

[7] T. Imae, Current Opinion in Colloid and Interface Science, 8 (2003) 307–314.

[8] W. Tang, Y. Huang, F. -L. Qing, Journal of Applied Polymer Science, 119 (2011) 84-92.

[9] Akihiko Asakawa, Masao Unoki, Takao Hirono, T. Takayanagi, Journal of Fluorine Chemistry, 104 (2000) 47-51.

DOI: 10.1016/s0022-1139(00)00226-8

[10] T. Araki, H. Sanemasa, M.K. e. al., in, US006069215, (2000).

[11] A. Franz Dirschl, B. Simpert Lüdemann, A. Edeltraud Schidek, in: US006387999B1, (2002).

[12] L. Chen, Y. Zhao, M. Deng, D. Yuan, H. Ni, W. Zhang, X. Wang, Polymer Bulletin, 64 (2009) 81-97.

[13] L. Chen, F. Wu, Journal of Saudi Chemical Society, (2011) 1-6.

[14] John J. Fitzgerald, Newark., in: US006180740B1, (2001).

[15] H. Ling, L. Junyan, Journal of Fluorine Chemistry, 129 (2008) 590-597.

[16] P. t. Xiong, D. p. Lu, P. z. Chen, H. z. Huang, R. Guan, Eur Polym J, 43 (2007) 2117-2126.

[17] L. Hao, Q. An, W. Xu, L. Huang, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 396 (2012) 83-89.

[18] Z. Xingshun, D. Xiaobin, Z. Junhua, Z. Chaohui, P. Yi, Zhu, Zhu, Yuhang, Peng, Acta Polymerica Sinica, (2004) 196-199.

[19] X. Cui, S. Zhong, J. Yan, C. Wang, H. Zhang, H. Wang, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 360 (2010) 41-46.

[20] P.A. Steward, J. Hearn, M.C. Wilkinson, Advances in colloid and interface science, 86 (2000) 195-267.