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HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 878Chemical and Mineralogical Characterizations of...

Chemical and Mineralogical Characterizations of Cobalt Precursor Recovered from Spent Lithium-Ion Batteries with Incineration Process

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Abstract:

The chemical and mineralogical characterizations of cobalt precursor recovered from spent lithium-ion batteries with incineration process was analyzed by X-ray photoelectron spectroscopy (XPS) and X-ray diffraction (XRD). It indicates that Co exists in the form of LiCoO₂. However, after thermal treatment, complex products including LiCoO₂, Co₃O₄, and Co₂AlO₄ etc. generated, in which Co₃O₄has strong signal. The XPS spectra shows that Li_(1-x)CoO₂ and LiCoO₂ are the main chemical state of Co in the original sample, but after thermal treatment, the chemical state changes to Co₃O₄. Besides, there are undecomposed Li_(1-x)CoO₂, CoF₃ and Co. Analyses indicate that Co is enriched after thermal treatment and chemical state of some Co have been certified.

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Periodical:

Advanced Materials Research (Volume 878)

Pages:

51-56

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.878.51

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Online since:

January 2014

Authors:

Tao Zhang, Ya Qun He, Lin Han Ge, Hong Li, Shan Wu

Keywords:

Incineration Process, LiCoO₂, Recycling, Spent Lithium-Ion Batteries

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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