Hydrothermal Treatment of Liquid Crystal Using a Batch Reactor

Article Preview

Abstract:

Liquid crystals, contained in Liquid Crystal Display (LCD), would cause undesirable impacts on the environment and human health if not treated properly. Converting the waste liquid crystal into harmless product has aroused worldwide attention. In the present work, hydrothermal technology was applied to treat the liquid crystal of 4-octoxy-4'-cyanobiphenyl, which is one of the most common used liquid crystals in LCDs. The experiment was carried out in a 5.7 mL stainless tube reactor and heated by an oven. The effect of reaction temperature and reaction time on degradation rate was evaluated and the analysis was conducted with High Performance Liquid Chromatography (HPLC). The degradation products in liquid phase were analyzed with Gas Chromatography/Mass Spectrometer (GC/MS). Results indicate that the degradation rate improved along with the increase of reaction temperature and reaction time. At 300 C and with the reaction time of 90 min, 99.8% of 4-octoxy-4'-cyanobiphenyl could be degraded into simple and environmental innocuous products and its environmental risks were finally eliminated.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

563-568

Citation:

Online since:

January 2014

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] R. Martin, S.H. Brigitte, W. Becker, Safe recovery of liquid crystal displays (LCDs) in compliance with WEEE. Electronics goes green 20074+, September 06-08, 2004 in Berlin.

Google Scholar

[2] K.L. Lin, W.K. Chang, T.C. Chang, C.H. Lee, C.H. Lin, Recycling thin film transistor liquid crystal display (TFT-LCD) waste glass produced as glass-ceramics, J. Clean. Prod. 17 (2009) 1499-1503.

DOI: 10.1016/j.jclepro.2009.05.012

Google Scholar

[3] K.L. Lin, W.J. Huang, J.L. Shie, T.C. Lee, K.S. Wang, C.H. Lee, The utilization of thin film transistor liquid crystal display waste glass as a pozzolanic material, J. Hazard. Mater. 163 (2009) 916-921.

DOI: 10.1016/j.jhazmat.2008.07.044

Google Scholar

[4] H.Y. Wang, A study of the effects of LCD glass sand on the properties of concrete, Waste Manage. 29 (2009) 335-341.

DOI: 10.1016/j.wasman.2008.03.005

Google Scholar

[5] R. Martin and Weinheim, U.S. patent, US 2007/0193414 A1. (2007).

Google Scholar

[6] Y.C. Chien, P.H. Shih, Emission of polycyclic aromatic hydrocarbons on the combustion of liquid crystal display components, J. Environ. Eng. -ASCE. 132 (2006) 1028-1033.

DOI: 10.1061/(asce)0733-9372(2006)132:9(1028)

Google Scholar

[7] Y.C. Chien, C.P. Liang, P.H. Shih, Emission of polycyclic aromatic hydrocarbons from the pyrolysis of liquid crystal wastes, J. Hazard. Mater. 170 (2009) 910-914.

DOI: 10.1016/j.jhazmat.2009.05.054

Google Scholar

[8] P.E. Savage, Organic chemical reactions in supercritical water, Chem. Rev. 99 (1999) 603-621.

Google Scholar

[9] P.G. Duan, E.P. Savage, Catalytic hydrotreatment of crude algal bio-oil in supercritical water, Appl. Catal. B - Environ. 104 (2011) 136-143.

DOI: 10.1016/j.apcatb.2011.02.020

Google Scholar

[10] A. Leybros, A. Roubaud, P. Guichardon, O. Boutin, Ion exchange resins destruction in a stirred supercritical water oxidation reactor, J. Supercrit. Fluid. 51 (2010) 369-375.

DOI: 10.1016/j.supflu.2009.08.017

Google Scholar

[11] E.U. Franck, Physicochemical properties of supercritical solvents, Berichte der Bunsengesellschaft für physikalische Chemie, 88 (1984) 820-825.

DOI: 10.1002/bbpc.19840880910

Google Scholar

[12] E.U. Franck, Fluids at high temperatures and pressures, Pure Appl. Chem. 59 (1987) 25-34.

Google Scholar

[13] P. Kritzer, E. Dinjus, An assessment of supercritical water oxidation (SCWO): Existing problems, possible solutions and new reactor concepts, Chem. Eng. J. 83 (2001) 207-214.

DOI: 10.1016/s1385-8947(00)00255-2

Google Scholar

[14] W.Z. He, G.M. Li, L.Z. Kong, H. Wang, J.W. Huang, J.C. Xu, Application of hydrothermal reaction in resource recovery of organic wastes, Resour. Conserv. Recy. 52 (2008) 691-699.

DOI: 10.1016/j.resconrec.2007.11.003

Google Scholar

[15] A. Leybrosa, A. Roubaud, P. Guichardon, O. Boutin, Supercritical water oxidation of ion exchange resins: degradation mechanisms, Process Saf. Environ. 88 (2010) 213-222.

DOI: 10.1016/j.psep.2009.11.001

Google Scholar

[16] A. Leybros, A. Roubaud, P. Guichardon, O. Boutin, Ion exchange resins destruction in a stirred supercritical water oxidation reactor, J. Supercrit. Fluid. 51 (2010) 369-375.

DOI: 10.1016/j.supflu.2009.08.017

Google Scholar

[17] J. Yin, G.M. Li, W.Z. He, J.W. Huang, M. Xu, Hydrothermal decomposition of brominated epoxy resin in waste printed circuit boards, J. Anal. Appl. Pyrol. 92 (2011) 131-136.

DOI: 10.1016/j.jaap.2011.05.005

Google Scholar

[18] M. Brebu, T. Bhaskar, A. Muto, Y. Sakata, Alkaline hydrothermal treatment of brominated high impact polystyrene (HIPS-Br) for bromine and bromine-free plastic recovery, Chemosphere, 64 (2006) 1021-1025.

DOI: 10.1016/j.chemosphere.2006.02.036

Google Scholar

[19] J.A. Onwudili, P.T. Williams, Degradation of brominated flame-retarded plastics (Br-ABS and Br-HIPS) in supercritical water, J. Supercrit. Fluid. 49 (2009) 356-368.

DOI: 10.1016/j.supflu.2009.03.006

Google Scholar

[20] V.M. Daskalaki, E.S. Timotheatou, A. Katsaounis, D. Kalderis, Degradation of Reactive Red 120 using hydrogen peroxide in subcritical water, Desalination, 274 (2011) 200-205.

DOI: 10.1016/j.desal.2011.02.009

Google Scholar

[21] E. Lindquist, Y. Yang, Degradation of benzoic acid and its derivatives in subcritical water, J. Chromatogr. A. 1218 (2011) 2146-2152.

DOI: 10.1016/j.chroma.2010.08.054

Google Scholar