Synthesis and Properties of Poly (N-arylenebenzimidazole ketone)s

Xiang Wang Cui; Lin Zhang

doi:10.4028/www.scientific.net/AMR.881-883.165

Paper Titles

Preparation of Manganese Dioxide Loaded Active Carbon and its Adsorption Dynamic
p.144

Progress on Synthesis and Application of Betaine Surfactants
p.148

Enantioselective Reformatsky Reaction between Cinnamaldehyde and Diflurinated Organozinc Reagent: Synthesis of Chiral γ,γ-difluoro-β-hydroxy Esters as Precursors of Statin Analogues
p.154

Electrocatalytic Sensing of Nitrate at Cu Nanosheets Electrodeposited on WO₃/Polyaniline Modified Electrode
p.159

Synthesis and Properties of Poly (N-arylenebenzimidazole ketone)s
p.165

Electrochemiluminescence Detection of Diphenhydramine Based on Tris(2,2-bipyridyl) Ruthenium(II) Immobilized on PEDOT-PSS Modified Electrode by Electrostatic Attraction Strategy
p.169

The Quantum Research on the Nucleophilic Reaction Activity of Polycyclic Aromatic Hydrocarbons
p.173

Hydrothermal Synthesis and Photocatalytic Activities of La-Doped BiVO₄ Microcakes
p.177

Synthesis, Crystal Structure and Fluorescence Study of 8-Dimethylaminomethyl-7-hydroxy-chromen-2-one①
p.181

HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 881-883Synthesis and Properties of Poly...

Synthesis and Properties of Poly (N-arylenebenzimidazole ketone)s

Abstract:

Two bis (benzimidazoyl) monomers were synthesized, and Poly (N-arylenebenzimidazole ketone) s were prepared by N-C coupling reaction that replaced the NH sites from the bis (benzimidazolyl) derivatives with activated difluorides monomers in sulfolane at 210 °C. All the resulting polymers showed easy solubility compared with traditional polybenzimidazoles. Differential scanning calorimetry and thermogravimetric measurements showed that the polymers had high glass transition temperatures (>240 °C), good thermostability and high decomposition temperatures (>460 °C).

You might also be interested in these eBooks

Chemical, Material and Metallurgical Engineering III

View Preview

Info:

Periodical:

Advanced Materials Research (Volumes 881-883)

Pages:

165-168

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.881-883.165

Citation:

Cite this paper

Online since:

January 2014

Authors:

Xiang Wang Cui, Lin Zhang

Keywords:

N-C Coupling Reaction, Poly(N-arylenebenzimidazole ketone)s, Solubility, Structure, Thermal Properities

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

Citation:

References

[1] I. Yamaguchi, K. Osakada, and T. Yamamoto, Macromolecules, Vol. 30 (1997), p.4288.

Google Scholar

[2] H. Vogel and C. S. Marvel, J. Polym. Sci. Part A: Polym. Chem., Vol. 34 (1996), p.1125.

Google Scholar

[3] R. H. Pater and P. A. Curto, Acta Astronaut, Vol. 61 (2007), p.1121.

Google Scholar

[4] H. L. Lin, J. R. Huang, S. H. Chan et al, J. Polym. Res., Vol. 19 (2012), p.9875.

Google Scholar

[5] J. M. Xu, C. L. Ren, Z. Wang et al, J. Polym. Res., Vol. 20 (2013), p.182.

Google Scholar

[6] Y. Gao, A. Hlil, A. S. Hay et al, Macromolecules, Vol. 40 (2007), p.4744.

Google Scholar

[7] A. R. Hill, S. Matsumura, and A. S. Hay, Macromolecules, Vol. 41 (2008), p. (1912).

Google Scholar

[8] Y. H. Qi, Y. Gao, A. S. Hay et al, J. Polym. Sci. Part A: Polym. Chem., Vol. 47 (2009), p. (1920).

Google Scholar

[9] Y. W. Xu, J. Tang, L. Zhang et al, Chin. Chem. Lett., Vol. 23 (2012), p.871.

Google Scholar

[10] Y. W. Xu, G. J. Chang, L. Zhang et al, Macromolecular Res., Vol. 21 (2013), p.681.

Google Scholar

[11] Y. W. Xu, J. Tang, L. Zhang et al, Poly. Int., Vol. 62 (2013), p.791.

Google Scholar

[12] J. R. Klaehn, T. A. Luther, E. S. Peterson et al, Macromolecules, Vol. 40 (2007), p.7487.

Google Scholar

[13] T. H. Kim, S. K. Kim, J. C. Lee et al, J. Membr. Sci., Vol. 323 (2008), p.362.

Google Scholar