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Theoretical Calculation of Dissolution Equilibrium for Galena in Pulp Solution
Abstract:
The dissolution equilibrium of galena within the entire pH range was theoretically calculated, which was based on coordination chemistry, thermodynamics and the mass balance principle of Pb2+ and S2- in pulp solution. The calculation result showed that the total lead concentration (CPbT) of galena decreased significantly with increasing pH below 7 or so; however, at pH of about 10, a reverse trend of CPbT may be observed. Within the pH range from 7 to 10, the CPbT of galena remained close and presents a minimum value of around 10-10 mol/L. This paper may provide a theoretical basis for the dissolution process of galena and its conditioning stage before benefication by adopting flotation method.
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1683-1686
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Online since:
January 2014
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© 2014 Trans Tech Publications Ltd. All Rights Reserved
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