Effective Hydrogenation of p-Chloronitrobenzene over Iridium Nanoparticles Entrapped in Aluminum Oxy-Hydroxide under Mild Conditions

Guang Yin Fan; Chun Zhang

doi:10.4028/www.scientific.net/AMR.881-883.267

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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 881-883Effective Hydrogenation of p-Chloronitrobenzene...

Effective Hydrogenation of p-Chloronitrobenzene over Iridium Nanoparticles Entrapped in Aluminum Oxy-Hydroxide under Mild Conditions

Abstract:

The Ir/AlO(OH) catalyst was prepared by sol-gel method and used for selective hydrogenation of p-chloronitrobenzene (p-CNB) to p-chloroniamine (p-CAN). The mechanism of p-CNB hydrogenation over the catalyst was discussed. The hydrogen bond between the surface hydroxyl groups of the catalyst and the nitrogen present in p-CNB facilitated the hydrogenation of nitro group. On the other hand, the formation of hydrogen bond between the hydrogenation product and water promotes the rapid desorption of the hydrogenation product on the surface of the catalyst. Thus the activity and selectivity were greatly promoted.

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Periodical:

Advanced Materials Research (Volumes 881-883)

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267-270

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.881-883.267

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Online since:

January 2014

Authors:

Guang Yin Fan*, Chun Zhang

Keywords:

Iridium Catalyst, p-Chloronitrobenzene, Selective Hydrogenation

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References

[1] X. Han, R. Zhou, G. Lai, X. Zheng: Catal. Today Vol. 93 (2004), p.433.

Google Scholar

[2] R. Nie, J. Wang, L. Wang, Y. Qin, P. Chen, Z. Hou: Carbon Vol. 50 (2011), p.586.

Google Scholar

[3] F.A. Harraz, S.E. El-Hout, H.M. Killa, I.A. Ibrahim: J. Catal. Vol. 286 (2012), p.184.

Google Scholar

[4] F. Zhang, J. Jin, X. Zhong, S. Li, J. Niu, R. Li, J. Ma: Green Chem., (2011) 0.

Google Scholar

[5] F. Chang, H. Kim, B. Lee, S. Park, J. Park: Tetrahedron Lett., Vol. 51 (2010), p.4250.

Google Scholar

[6] G. -Y. Fan, L. Zhang, H. -Y. Fu, M. -L. Yuan, R. -X. Li, H. Chen, X. -J. Li: Catal. Commun. Vol. 11 (2010), p.451.

Google Scholar

[7] I.S. Park, M.S. Kwon, K.Y. Kang, J.S. Lee, J. Park: Adv. Synth. Catal., Vol. 349 (2007), p. (2039).

Google Scholar

[8] H. Hou, Y. Xie, Q. Yang, Q. Guo, C. Tan: Nanotechnology Vol. 16 (2005), p.741.

Google Scholar

[9] J. Ning, J. Xu, J. Liu, H. Miao, H. Ma, C. Chen, X. Li, L. Zhou, W. Yu: Catal. Commun. Vol. 8 (2007), p.1763.

Google Scholar

[10] M. Pietrowski, M. Zieliński, M. Wojciechowska: Catal. Lett., Vol. 128 (2009), p.31.

Google Scholar