Paper Titles

Study on Solid Surface Sizing Agent for Paper
p.233

Study on the Photocatalytic Oxidation of Reactive Brilliant Blue X-BR with Lanthanum-Modified ZnO-TiO₂
p.237

Study on the Pigging Process of Rich Gas Pipeline
p.242

Synthesis and Characterization of Luminescence Eu³⁺/Polyurethane Composite Material
p.247

Synthesis and Properties of Composite Membranes for Polymer Electrolyte Membrane Fuel Cells
p.251

UV Protection Property of Colorant from Lac for Silk Fabric Dyeing by Cold Pad-Batch: The Influence of Metal Mordants Concentration
p.257

Evaluation of NO_X Removal from Simulated Flue Gas by "Absorption-Oxidation-Reduction" Method
p.261

Application Study of Viscoelastic Damping Material for the Anti-Galloping of Overhead Transmission Lines
p.269

Effect of Latent Heat Related to Solidification Kinetics on Heat Transfer during Solidification of Al Alloy
p.273

HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 884-885Synthesis and Properties of Composite Membranes...

Synthesis and Properties of Composite Membranes for Polymer Electrolyte Membrane Fuel Cells

Article Preview

Abstract:

The paper is devoted to the sol-gel synthesis of proton conductive organic-silicon composite membranes based on tetraethyl orthosilicate (TEOS) and copolymers of 2-methyl-5-vinylpyridine and vinyl chloride (MVP-VC), 2-methyl-5-vinylpyridine and vinyl acetate (MVP-VA), copolymers of ethylene glycol vinyl glycidyl ether and styrene (KS-1 and KS-2), and nitrogen-containing heteroaromatic derivatives of sulfonic acids: 2-phenyl-5-benzimidazolsulfonic acid (PBISA) and pyridine-3-sulfonic acid (PSA). Properties of synthesized membranes, such as proton conductivity, activation energy, ion exchange capacity, dimensional stability have been investigated.

You might also be interested in these eBooks

Biotechnology, Chemical and Materials Engineering III

Info:

Periodical:

Advanced Materials Research (Volumes 884-885)

Pages:

251-256

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.884-885.251

Citation:

Cite this paper

Online since:

January 2014

Authors:

Alexandra N. Chesnokova*, Oksana V. Lebedeva, Yury N. Pozhidaev, Nikolay A. Ivanov, Alexander E. Rzhechitskii

Keywords:

Fuel Cell (FC), Impedance Spectroscopy, Organic-Silicon Composite, Proton-Conducting Membrane, Solgel Synthesis

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Barbir F.: PEM Fuel Cells: Theory and Practice, Academic Press (2012), 518 p.

[2] Zhao T.S., Kreuer K. -D., Nguyen T.: Advances in Fuel Cells, Elsevier (2007), 499 p.

[3] Hickner M.A., Ghassemi H., Kim Yu S., Einsla B. R., and McGrath J. E.: Alternative Polymer Systems for Proton Exchange Membranes (PEMs), Chem. Rev., Vol. 104(2004) , pp.4587-4612.

DOI: 10.1021/cr020711a

[4] Neburchilov V., Martin J., Wang H., Zhang J.: A review of polymer electrolyte membranes for direct methanol fuel cells, Journal of Power Sources, Vol. 169 (2007), p.221–238.

DOI: 10.1016/j.jpowsour.2007.03.044

[5] Mel'nikova N. A., Postnov V. N., Glumov O. V., Murin I. V.: Proton conductivity of composites based on Nafion and silica matrices with a chemically modified surface, Russian Journal of Electrochemistry, Vol. 49, Issue 7 (2013), pp.676-679.

DOI: 10.1134/s1023193513070100

[6] Aparicio M., Jitianu A., Klein L. C.: Sol-Gel Processing for Conventional and Alternative Energy, New York: Springer (2012), 399 p.

DOI: 10.1007/978-1-4614-1957-0

[7] Innocenzi, P., Zub Y.L., and Kessler V.G. (eds. ): Sol-gel methods for Materials Processing: Focusing on Materials for Pollution Control, Water Purification, and Soil Remediation Springer, New York (2008), 508 p.

DOI: 10.1007/978-1-4020-8514-7

[8] Pozhidaev Y., Lebedeva O., Bochkareva S., and Sipkina E.: Hybrid Composites from Silicon Materials and Nitrogenous Heterocyclic Polybases, Adv. Sci. Lett., Vol. 19 (2013), pp.309-312.

DOI: 10.1166/asl.2013.4683

[9] Lebedeva O., Pozhidaev Yu., Sipkina E., Chesnokova A. and Ivanov N.: Copolymers and Proton Conducting Films Based on N-Vinylpyrazole, Advanced Materials Research, Vol. 749 (2013), pp.71-76.

DOI: 10.4028/www.scientific.net/amr.749.71

[10] Lebedeva O.V., Pozhidaev Yu. N., Shaglaeva N. S., Pozdnyakov A. S. and Bochkareva S. S.: Polyelectrolytes based on nitrogenous bases, Theoretical Foundations of Chemical Engineering. Vol. 44 (2010), p.786.

DOI: 10.1134/s0040579510050258

[11] Pozhidaev Yu., Lebedeva O., Sypkina E., Chesnokova A., Ivanov N. Synthesis and Properties of Hybride Materials for Ion-exchange and Complexing Membranes / Advanced Materials Research, Vol. 749 (2013), pp.283-288.

DOI: 10.4028/www.scientific.net/amr.749.283

[12] Pozhidaev Yu., Vlasova N., Vasilyeva I. and Voronkov M. Determination of noble metals in rocks and ores using adsorbent PSTM-3T / Adv. Sci. Lett. Vol. 19 (2013), pp.615-618.

DOI: 10.1166/asl.2013.4730

[13] Lebedeva O.V., Pozhidaev Yu.N., Sultangareev R.G., Pozdnyakov A.S., Bochkareva S.S., Orkhokova E.A., Shaglaeva N.S. Polymeric electrolytes based on vinylpyridines / Russian Journal of Applied Chemistry Vol. 82, Issue 11 (2009), p.2015-(2019).

DOI: 10.1134/s1070427209110214

[14] Raskulova, T. V.; Volkova, L. I.; Moskaleva, O. N.; Khaliullin, A. K. Properties and Application Prospects of 1-(Vinyloxyalkoxy)propylene 2, 3-Oxide Copolymers / Russian Journal of Applied Chemistry, Vol. 75 (3) (2002), p.457 – 460.

DOI: 10.1023/a:1016111325357

[15] Haile S. M.: Fuel cell materials and components, Acta Materialia, Vol. 51(2003), pp.5981-6000.

[16] Voronkov M. G., Mileshkevich V. P. and Yuzhelevskii Yu. A.: The Siloxane Bond, Physical Properties and Chemical Transformations, Plenum Publishing Corporation, New York (1978).

DOI: 10.1080/00945717908069783