Laser-Induced Copper Deposition from Solution: Removing the Thermodynamic Restrictions

Article Preview

Abstract:

s. The study showed that organic alcohols with 1,2,3,5,6 hydroxyl groups can be used as reducing agents for laser-induced copper deposition from solutions (LCLD).Multiatomic alcohols, sorbitol, xylitol, and glycerol, are shown to be effective reducing agents for performing LCLD at glass-ceramic surfaces unless they are weak reductants. Hypothesis of 2-photon photoeffect during laser induced copper deposition was discussed. Using the described dechnique one can obtain high-conductivity copper micro wires on dielectric surfaces for microelectronics and sensor applications

You might also be interested in these eBooks

Info:

Periodical:

Pages:

45-51

Citation:

Online since:

February 2014

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] V.A. Kochemirovsky, E.M. Khairullina, S.V. Safonov, L.S. Logunov, I.I. Tumkin and L.G. Menchikov, The influence of non-ionic surfactants on laser-induced copper deposition, Appl. Surf. Sci. 280 (2013) 494-499.

DOI: 10.1016/j.apsusc.2013.05.016

Google Scholar

[2] V.A. Kochemirovsky, S.V. Safonov, M.K. Strukov, I.I. Tumkin, L.S. Logunov and L.G. Menchikov, Glycerol as a ligand for the laser-induced liquid phase deposition of copper, Glass Phys. Chem. 39(4) (2013) 403-408.

DOI: 10.1134/s1087659613040111

Google Scholar

[3] A. Manshina, , A. Povolotskiy, T. Ivanova, A. Kurochkin, Y. Tver'yanovich, D. Kim, M. Kim and S.C. Kwon, CuCl2-based liquid electrolyte precursor for laser-induced metal deposition, Laser Phys. Lett. 4 (3) (2007) 242–246.

DOI: 10.1002/lapl.200610093

Google Scholar

[4] A.A. Man'shina, A.V. Povolotskiy, T.Y. Ivanova, A.V. Kurochkin, Y. S. Tver'yanovich, D. Kim, M. Kim and S. Kwon, Laser-induced copper deposition on the surface of an oxide glass from an electrolyte solution, Glass Phys. Chem. 33 (3) (2007).

DOI: 10.1134/s1087659607030030

Google Scholar

[5] A.A. Manshina, A.V. Povolotskiy, T.Y. Ivanova, Y.S. Tver'yanovich, S.P. Tunik, D. Kim, M. Kim, and S.C. Kwon, Effect of salt precursor on laser-assisted copper deposition, Appl. Phys. A-Mater. 89 (3) (2007) 755–759.

DOI: 10.1007/s00339-007-4164-9

Google Scholar

[6] V.A. Kochemirovsky, L.S. Logunov, S.V. Safonov, I. I. Tumkin, Y.S. Tver'yanovich and L.G. Menchikov, Sorbitol as an efficient reducing agent for laser-induced copper deposition, Appl. Surf. Sci. 259 (2012) 55–58.

DOI: 10.1016/j.apsusc.2012.06.085

Google Scholar

[7] R. Ramanauskas, I. Jurgaitienst and A. Vaskelis, Electrocatalytic oxidation of formaldehyde on copper single crystal electrodes in alkaline solutions, Electrochim. Acta 42 (2) (1997) 191–195.

DOI: 10.1016/0013-4686(96)00143-0

Google Scholar

[8] M. Z. Luo and R. P. Baldwin, Characterization of carbohydrate oxidation at copper electrodes, J. Electroanal. Chem. 387 (1–2) (1995) 87–94.

Google Scholar

[9] K. Kordas, J. Bekesi, R. Vajtai, L. Nanai, S. Leppavuouri, A. Uusimaki, K. Bali, T. F. George, G. Galbacs, and F. Ignacz, Laser-assisted metal deposition from liquid-phase precursors on polymers, Appl. Surf. Sci. 172 (2001) 178–189.

DOI: 10.1016/s0169-4332(00)00852-7

Google Scholar

[10] R. von Gutfeld and K. Sheppard, Electrochemical microfabrication by laser-enhanced photothermal processes, IBM J. Res. Dev. 42 (5) (1998) 639–653.

DOI: 10.1147/rd.425.0639

Google Scholar

[11] V.A. Kochemirovsky, L.G. Menchikov, A.G. Kuz'min, S.V. Safonov, I.I. Tumkin, and Y.S. Tver'yanovich, Side reactions during laser-induced deposition of copper from aqueous solutions of CuII complexes, Rus. Chem. B+ 61 (5) (2012) 1041-1047.

DOI: 10.1007/s11172-012-0133-3

Google Scholar

[12] E. Norkus, V. Kepenienė and I. Stalnioniene, Application of environment-friendly ligands for alkaline electroless copper plating systems : A comparative study of electroless copper deposition using D- , L- and DL-tartrate as Cu (II) ligands, Chemija 23 (3) (2012).

DOI: 10.1149/ma2014-01/9/521

Google Scholar

[13] A. M. Brodsky and Y.V. Pleskov, Electron photoemission at a metal-electrolyte solution interface. Progress in surface science, New York : Pergamon Press, (1972).

DOI: 10.1016/0079-6816(72)90010-x

Google Scholar