Effect of High-Energy Ball Milling on the Charge-Discharge Behaviour of LiCo0.3Ni0.7O2

Kelimah Elong; Norlida Kamarulzaman

doi:10.4028/www.scientific.net/AMR.895.400

Paper Titles

The Pumping Parameters for Er-Doped Tellurite Glass
p.375

Effect of Boron Carbide Addition on the Strength and Physical Properties of Concrete
p.385

The Thermoluminescence Response of Dy Doped Calcium Borate Glass Subjected to 6MV Photon Irradiation
p.390

Absorption Spectra of Neodymium Doped Tellurite Glass
p.395

Effect of High-Energy Ball Milling on the Charge-Discharge Behaviour of LiCo_0.3Ni_0.7O₂
p.400

Fractal Analysis of Morphological Image of Organic Phthalocyanine Tetrasulfonic Acid Tetrasodium (TsNiPc) Film
p.407

Calculation of Confined Electron and Hole States in a Strained InAs-GaAs Pyramidal Quantum Dot System Based on Effective Mass Approximation
p.411

Discontinuity Mass of Finite Difference Calculation in InAs-GaAs Quantum Dots
p.415

Magnetic Ground State and Electronic Structure Calculations of PbMnO₃ Using DFT
p.420

HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 895Effect of High-Energy Ball Milling on the...

Effect of High-Energy Ball Milling on the Charge-Discharge Behaviour of LiCo_0.3Ni_0.7O₂

Abstract:

Li-ion cathode materials in the nanodimension should show improvement in capacity retention from the normal material. This is because the electrochemical performance of the cathode material in lithium secondary batteries depends on the electrochemical redox reaction which is affected by the surface area to volume ratio of the particles. In this work, LiCo_0.3Ni_0.7O₂powder will be prepared via a self-propagating combustion method and the high-energy ball milling method will be used to prepare LiCo_0.3Ni_0.7O₂nanopowders. X-Ray Diffraction (XRD) and Field Emission Scanning Electron Microscopy (FESEM) are used to characterize the materials. The materials are observed to be phase pure. Li-ion cells are then fabricated and tested. The cells are subjected to a series of charge-discharge cycling in the voltage range of 3.0 to 4.3 V. It was found that the nanomaterial exhibit specific capacities less than that of the normal material.

You might also be interested in these eBooks

View Preview

Info:

Periodical:

Advanced Materials Research (Volume 895)

Pages:

400-403

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.895.400

Citation:

Cite this paper

Online since:

February 2014

Authors:

Kelimah Elong, Norlida Kamarulzaman

Keywords:

Ball Milling, Lithium-Ion Battery, Nanopowder, Particle Size

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

Citation:

References

[1] G.T.K. Fey, R.F. Shiu, T.P. Kumar and C.L. Chen, Preparation Preparation and characterization of lithium nickel cobalt oxide powders via a wet chemistry processing, Mater. Sci. Engineering B100 (2003), 234-243.

DOI: 10.1016/s0921-5107(03)00109-0

Google Scholar

[2] J. Su, Y. Su and M. Guo, Synthesis of layered LiNi0. 7Co0. 3O2 cathode materials by a homogeneous precipitation route, J. New Mat. Electrochem. Systems 10 (2007), 91-94.

Google Scholar

[3] N. Kamarulzaman, R. Yusooff, N. Kamarudin, N.H. Shaari, N.A. Abdul Aziz, M.A. Bustam, N. Blagojevic, M. Elcombe, M. Blackford, M. Avdeev and A.K. Arof, Investigation of cell parameters, microstructures and electrochemical behaviour of LiMn2O4 normal and nano powders, J. Power Sources 188 (2009).

DOI: 10.1016/j.jpowsour.2008.10.139

Google Scholar

[4] N. Kamarulzaman , R.H.Y. Subban, K. Ismail, N. Othman, W.J. Basirun, M.A. Bustam, S.A. Puad, R. Yusof and A.F. M Fadzil, Characterization and microstructural studies of LiFeSO8 synthesized by the self propagating high temperature combustion method, Ionics 11 (2005).

DOI: 10.1007/bf02430264

Google Scholar

[5] S. Castro-Garcia, C. Julien, M.A. Senaris-Rodriguez, and D. Mazas-Brandariz, Influence of the Synthesis Method on the Structural and Electrochemical Properties of LiCol-yNiyO2 Oxides, Ionic 6 (2000), 434-441.

DOI: 10.1007/bf02374164

Google Scholar

[6] G.T.K. Fey, R.F. Shiu, V. Subramaniam, J.G. Chen and C.L. Chen, LiCo0. 8Ni0. 2O2 cathode materials synthesized by the maleic acid assisted sol-gel method or lithium batteries, J. Power Sources 102 (2003), 265-272.

DOI: 10.1016/s0378-7753(01)00859-x

Google Scholar

[7] X.M. Liu, W.L. Gao and B.M. Ji, Synthesis of LiNi1/3Co1/3Mn1/3O2 nanoparticles by modified Pechini method and their enhanced rate capability, J. Sol-Gel Sci Technol. 61 (2012), 56-62.

DOI: 10.1007/s10971-011-2590-9

Google Scholar