Photodegradation of Humic Acid and its Effect on the Property of Copper Binding

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Humic acid plays an important role in regualting the physical, chemical and biological properties in aquatic systems. In this paper, photochemical degradation of humic acid and its effect on the copper binding coefficient were studied. Results showed that the copper binding coefficient decreased with increased irradiation time. The decrease of copper binding coefficient was significantly correlated with the humic acid structure parameters (SUVA270 and E2/E3) during the photodegradation. It suggested that photodegradation of humic acid may have effects on the bioaccumulation of copper and hence its toxicity to aquatic organisms.

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470-473

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February 2014

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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[1] S. Inaba, C. Takenaka, Effects of dissolved organic matter on toxicity and bioavailability of copper for lettuce sprouts, Environ. Int. 31 (2005) 603-608.

DOI: 10.1016/j.envint.2004.10.017

Google Scholar

[2] P. Stathi, Y. Deligiannakis, Humic acid-inspired hybrid materials as heavy metal absorbents, J. Colloid Interface Sci. 351 (2010) 239-247.

DOI: 10.1016/j.jcis.2010.06.023

Google Scholar

[3] M. Martínez-Zapata, C. Aristizábal, G. Peñuela, Photodegradation of the endocrine-disrupting chemicals 4n-nonylphenol and triclosan by simulated solar UV irradiation in aqueous solutions with Fe(III) and in the absence/presence of humic acids, Journal of Photochemistry and Photobiology A: Chemistry 251 (2013).

DOI: 10.1016/j.jphotochem.2012.10.009

Google Scholar

[4] C. Baduel, M.E. Monge, D. Voisin, J.L. Jaffrezo, C. George, I.E. Haddad, N. Marchand, B. D'Anna, Oxidation of atmospheric humic like substances by ozone: a kinetic and structural analysis approach, Environmental Science & Technology 45 (2011).

DOI: 10.1021/es200587z

Google Scholar

[5] P. Sánchez-Marín, J.I. Lorenzo, R. Blust, R. Beiras, Humic Acids Increase Dissolved Lead Bioavailability for Marine Invertebrates, Environmental Science & Technology 41 (2007) 5679-5684.

DOI: 10.1021/es070088h

Google Scholar

[6] T. Lou, H. Xie, Photochemical alteration of the molecular weight of dissolved organic matter, Chemosphere 65 (2006) 2333-2342.

DOI: 10.1016/j.chemosphere.2006.05.001

Google Scholar

[7] N.D. Bryan, D.L. Jones, R.E. Keepax, D.H. Farrelly, L.G. Abrahamsen, A. Pitois, P. Ivanov, P. Warwick, N. Evans, The role of humic non-exchangeable binding in the promotion of metal ion transport in groundwaters in the environment, J. Environ. Monit. 9 (2007).

DOI: 10.1039/b701891f

Google Scholar

[8] T. Lou, H. Xie, G. Chen, J.P. Gagne, Effects of photodegradation of dissolved organic matter on the binding of benzo(a)pyrene, Chemosphere 64 (2006) 1204-1211.

DOI: 10.1016/j.chemosphere.2005.11.043

Google Scholar

[9] Y.P. Chin, G. Aiken, E. O'Loughlin, Molecular weight, polydispersity, and spectroscopic properties of aquatic humic substances, Environmental Science & Technology 28 (1994) 1853-1858.

DOI: 10.1021/es00060a015

Google Scholar

[10] H. Chen, R. Berndtsson, M. Ma, K. Zhu, Characterization of insolubilized humic acid and its sorption behaviors, Environmental Geology 57 (2008) 1847-1853.

DOI: 10.1007/s00254-008-1472-0

Google Scholar

[11] B.J. Dalzell, E.C. Minor, K.M. Mopper, Photodegradation of estuarine dissolved organic matter: a multi-method assessment of DOM transformation, Organic Geochemistry 40 (2009) 243-257.

DOI: 10.1016/j.orggeochem.2008.10.003

Google Scholar

[12] J.R. Helms, A. Stubbins, E.M. Perdue, N.W. Green, H. Chen, K. Mopper, Photochemical bleaching of oceanic dissolved organic matter and its effect on absorption spectral slope and fluorescence, Marine Chemistry 155 (2013) 81-91.

DOI: 10.1016/j.marchem.2013.05.015

Google Scholar