Effect of Temperature on Solubility of WO3 in the NaCl-KCl-NaF-WO3 Molten Salt

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The solubility of WO3 in NaCl-KCl-NaF-WO3 molten salt system was measured by isothermal saturation method. The results show that in the molten salt system the solubility of WO3 increased with the increase of temperature from 700 °C to 820 °C, and the relationship between solubility and temperature is approximately linear. As shown in the XRD pattern, there are NaCl, KCl, NaF, WO3, Na5W3O9F5, Na3WO3F3 and NaWO3F in the molten salt, so the dissolution of WO3 is the result of both physical dissolution and chemical dissolution.

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171-174

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March 2014

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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[1] S. Y. Shen. The ionic melt chemistry [M], Beijing: Metallurgical Industry Press, 1986: 48.

Google Scholar

[2] S. Z. Duan, Z. Y. Qiao. Molten salt chemistry: Principles and application [M]. Beijing: Metallurgical Industry Press, 1990: 201.

Google Scholar

[3] N. X. Feng, X. C. Liu, Y. Sun. Chinese Journal of Materials Research Vol. 15(2001), p.459.

Google Scholar

[4] N. X. Feng, Y. Sun, G. J. Ge. Rare Metals, Vol. 25(2001), p.374.

Google Scholar

[5] K. Nitta, S. Inazawa, K. Okada, H. Nakajima, T. Nohira, R. Hagiwara. Electrochim. Acta, Vol. 53(2007), p.20.

Google Scholar

[6] K. Nitta, T. Nohira, R. Hagiwara, M. Majima, S. Inazawa. Electrochim. Acta, Vol. 55(2010), p.1278.

Google Scholar