Synthesis and Characterization of a New Type of Highnuclear Lanthanide – Cobalt Carboxylate Cluster Complex

Oyun Erdene Byambasuren; Feng Hua Bai; Yin Xia Zhang; Hai Quan Su

doi:10.4028/www.scientific.net/AMR.908.42

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Synthesis and Characterization of a New Type of Highnuclear Lanthanide – Cobalt Carboxylate Cluster Complex
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HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 908Synthesis and Characterization of a New Type of...

Synthesis and Characterization of a New Type of Highnuclear Lanthanide – Cobalt Carboxylate Cluster Complex

Abstract:

A new heteronuclear Ln-Co carbonyl cluster, Ce₄Yb₂(μ₃-L)₄(CF₃COO)₈(DMF)₆Co (L=(CO)₆Co₂CC(COO)₂^-), has been synthesized by reaction of (CO)₆Co₂CC(COOH)₂ with Ce (OOCCF₃)₃2H₂O and Yb (OOCCF₃)₃2H₂O. The cluster structure was characterized by single-crystal X-ray diffraction and IR. The crystal is monoclinic crystal system and C2/c space group. X-ray analysis revealed that the heterometallic cluster belonged to a rare class of Ln-Co carbonyl cluster bridged by carboxylate groups of carbonyl cluster ligands. The cluster was monometric unit and exhibited cage-like configuration.

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Periodical:

Advanced Materials Research (Volume 908)

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42-45

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https://doi.org/10.4028/www.scientific.net/AMR.908.42

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Online since:

March 2014

Authors:

Oyun Erdene Byambasuren, Feng Hua Bai, Yin Xia Zhang, Hai Quan Su*

Keywords:

Cobalt Carbonyl Cluster, Lanthanide-Transition Cluster, Ligand

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