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Electrochemical Fixation of Carbon Dioxide for Synthesis Dimethyl Carbonate in Ionic Liquid BMimBr

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Abstract:

In the one compartment electrochemical cell equipped with platinum electrodes electrochemical fixation carbon dioxide was conducted under ambient conditions. Ionic liquid BMimBr is supporting electrolyte. The aimed product dimethyl carbonate was electrosynthesized in a dialkylimidazolium ionic liquids-propylene oxide-methanol system under normal temperature and pressure. The result indicated that the highest yield of 37.8 % was obtained in the condition of working temperature 30 °C, electrolytic voltage 5.5 V, the mass of CH3OH 0.484 mol, propylene oxide 0.052 mol and bmimBr 0.059 mol.

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Periodical:

Advanced Materials Research (Volumes 953-954)

Pages:

1180-1183

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.953-954.1180

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Online since:

June 2014

Authors:

Dan Dan Yuan, Bin Bin Yuan, Hua Song, Rui Xia Niu, Yan Xiu Liu

Keywords:

Carbon Dioxide, Dimethyl Carbonate, Ionic Liquid (IL), Propylene Oxide

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