Synthesis and Electrical Conductivity Measurement of Polyaniline / Vermiculite Nanocomposites

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A series of polyaniline/vermiculite nanocomposites was synthesized. The interlayer space of vermiculite was initially increased by the insertion of dioctadecyl dimethyl ammonium bromide, and then the aniline monomers were inserted into the interlayer space of vermiculite replacing dioctadecyl dimethyl ammonium cations. The polyaniline/vermiculite nanocomposites materials were prepared via in situ polymerization of the aniline monomers in the interlayer space of vermiculite. The as-synthesized polyaniline/vermiculite nanocomposite materials were characterized by X-ray diffraction analysis, infrared spectroscopy, and electrical conductivity measurement. The results indicated that the vermiculite was peeled off into the polyaniline. The introduction of vermiculite nanosheets showed a beneficial effect on the electrical conductivity of polyaniline.

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221-226

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January 2010

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© 2010 Trans Tech Publications Ltd. All Rights Reserved

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[1] M.A. Bavio, T. Kessler and A.M. Castro Luna: Journal of Colloid and Interface Science, Vol. 352 (2008), p.414.

Google Scholar

[2] Techeng Mo, Hongcen Wang, Sanyan Chen, et al.: Ceramics International, Vol. 34 (2008), p.1767.

Google Scholar

[3] X. S. Du, M. Xiao and Y. Z. Meng: European Polymer Journal, Vol. 40 (2004), p.1489.

Google Scholar

[4] Yong Taik Lim, Jong Hyeok Park and O Ok Park: Journal of Colloid and Interface Science, Vol. 245 (2002), p.198.

Google Scholar

[5] Dongkyu Lee and Kookheon Char: Polymer Degradation and Stability, Vol. 75 (2002), p.555.

Google Scholar

[6] B. H. Kim, J. H. Jung, J. W. Kim, et al.: Synthetic Metals, Vol. 121 (2001), p.1311.

Google Scholar

[7] Q. Wu, Z. Xue, Z. Qi and F. Wang: Polymer, Vol. 41 (2000), p. (2029).

Google Scholar

[8] Dong Hyun Song, Hyung Min Lee, Ki-Ho Lee and Hyoung Jin Choi: Journal of Physics and Chemistry of Solids, Vol. 69 (2008), p.1383.

Google Scholar

[9] Kung-Chin Chang, Guang-Way Jang, Chih-Wei Peng, et al.: Electrochimica Acta, Vol. 52 (2007), p.5191.

Google Scholar

[10] Daofu Liu, Xusheng Du and Yuezhong Meng: Materials Letters, Vol. 15 (2006), p.1847.

Google Scholar

[11] J.D. Sudha and T.S. Sasikala: Polymer, Vol. 48 (2007), p.338.

Google Scholar

[12] Gustavo M. do Nascimento, Vera R.L. Constantino, Richard Landers, et al.: Temperini Polymer, Vol. 47 (2006), p.6131.

Google Scholar

[13] Shoji Yoshimoto, Fumihiko Ohashi, Yasushi Ohnishi, et al.: Synthetic Metals, Vol. 145 (2004), p.265.

Google Scholar

[14] W. Jia, E. Segal, D. Kornemandel, et al.: Synthetic Metals, Vol. 128 (2002), p.115.

Google Scholar

[15] Tongjiang Peng, Pu Wan, Zhaolu Pan, et al.: Acta petrol. Mineral, Vol. 15 (1996), p.250.

Google Scholar