Wetting Property of Cu-Doped ZnO with Micro-/Nano-Structures

Article Preview

Abstract:

ZnO with different morphologies were formed on Zn foils immersed in various concentrations of CuSO4 solutions. Then the specimens were heated at temperature of 200~600°C in air for 3h. The morphologies of as-prepared specimens were characterized by a scanning electron microscope (SEM). Water wetting angles on the specimens were measured. The results indicate that the morphologies of ZnO on the Zn foils relate to the CuSO4 concentration of in solutions. The morphologies on the specimens with dual-scale (nanoand micro) structure have higher wetting angles than those with flat structure. The water wetting angles can reduce with the increase in annealing temperatures of immersed specimens. The water wetting angles increase with keeping immersed specimens at room temperatures. The change of the wetting angle is explained by absorption of organic carbon on specimen surface and the geometric structure of the surface.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 960-961)

Pages:

61-64

Citation:

Online since:

June 2014

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] R. N. Wenzel, Surface roughness and contact angle, J. Phys. Colloid Chem., vol. 53, pp.1466-1467, (1949).

DOI: 10.1021/j150474a015

Google Scholar

[2] D. L. Tian, J. Zhai, Y. L. Song, and L. Jiang, Photoelectric Cooperative Induced Wetting on Aligned-Nanopore Arrays for Liquid Reprography, Adv. Funct. Mater. vol. 21, p.4519–4526, (2011).

DOI: 10.1002/adfm.201101008

Google Scholar

[3] M. E. Abdelsalam, Wetting of regularly structured gold surfaces, Langmuir, vol. 21, p.1753, May (2005).

DOI: 10.1021/la047468q

Google Scholar

[4] A. M. Gaudin, Flotation, McGraw-Hill Book Company Inc, New York, 1957, p.388.

Google Scholar

[5] T. Sun, L. Feng, X. Gao, and L. Jiang, Bioinspired Surfaces with Special Wettability, Acc. Chem. Res. Vol. 38, pp.644-645, Oct. (2005).

DOI: 10.1021/ar040224c

Google Scholar

[6] J. P. Wang, C. H. Xu, Y. F. You, Z. S. Si, D. L. Li, and S. Q. Shi, Fast Synthesis of Cu-doped ZnO Nanosheets at Ambient Condition, Cryst. Res. Technol. Vol. 48, p.273–278, May (2013).

DOI: 10.1002/crat.201200469

Google Scholar

[7] Y L Liu, J. P. Wang, C. H. Xu, The Effects of Annealing Temperature on Cu-doped ZnO Nanosheets, unpublished.

Google Scholar

[8] A. B. D. Cassie, Wettability of porous surfaces, Trans. Faraday Soc., vol. 40, p.546, (1944).

DOI: 10.1039/tf9444000546

Google Scholar