Variation in Pore Structure Characteristics with Composition in the High Volatile Bituminous Coal of Binchang Area

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Pore structure characteristics and the effect of lithotype and maceral on pore for three types of high-volatile bituminous coals from Binchang area were investigated by combined low-temperature nitrogen adsorption/desorption, nuclear magnetic resonance (NMR), scanning electron microscope (SEM) and maceral analysis. The low temperature N2 adsorption/desorption test results show that: micropores are more abundant than transitional pores with high BET surface area; two types of pore structures can be identified by adsorption/desorption isotherms; Pore morphology is mainly represented by well-connected, ink-bottled, cylindrical and parallel plate pores. NMR T2 distributions at full saturated condition are apparent or less obvious trimodal and three types of T2 distributions are identified; Seepage pores are better developed when compared with the middle-high rank coal. Further research found that the three coal lithotypes are featured by remarkably different pore structure characteristics and maceral contents of coal are linearly correlated to some of pore structure parameters.

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Advanced Materials Research (Volumes 962-965)

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890-898

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June 2014

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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[1] J.E. Warren and P.J. Root. The behavior of naturally fractured reservoirs[J]. Society of Petroleum Engineers Journal, 1963, 245-255.

DOI: 10.2118/426-pa

Google Scholar

[2] M. Mastalerz, A. Drobniak, D. Strąpoć, et al. Variations in pore characteristics in high volatile bituminous coals: implications for coal bed gas content. International Journal of Coal Geology, 2008, 76: 205-216.

DOI: 10.1016/j.coal.2008.07.006

Google Scholar

[3] K.S.W. Sing. Physisorption of nitrogen by porous materials. Journal of Porous Materials 1995, 2: 5–8.

Google Scholar

[4] Y.D. Cai, D.M. Liu, Y.B. Yao, et al. Geological controls on prediction of coalbed methane of No. 3 coal seam in Southern Qinshui Basin, North China[J]. International Journal of Coal Geology, 2011, 88(2): 101-112.

DOI: 10.1016/j.coal.2011.08.009

Google Scholar

[5] Y.M. Lv, D.Z. Tang, H. Xu, et al. Production characteristics and the key factors in high-rank coalbed methane fields: A case study on the Fanzhuang Block, Southern Qinshui Basin, China. International Journal of Coal Geology, 2012, 96-97: 93-108.

DOI: 10.1016/j.coal.2012.03.009

Google Scholar

[6] X.B. Su, L.P. Zhang, R.L. Zhang. The abnormal pressure regime of the Pennsylvanian No. 8 coalbed methane reservoir in Liulin–Wupu district, eastern Ordos Basin, China[J]. International Journal of Coal Geology, 2003, 53(4): 227-239.

DOI: 10.1016/s0166-5162(03)00015-6

Google Scholar

[7] C.T. Wei, Y. Qin, G.X. Wang, et al. Numerical simulation of coalbed methane generation, dissipation and retention in SE edge of Ordos Basin, China[J]. International Journal of Coal Geology, 2010, 82(3): 147-159.

DOI: 10.1016/j.coal.2009.12.005

Google Scholar

[8] S. Li, D.Z. Tang, H. Xu, et al. Comparative Analysis of Pore and Fracture System of Coal Reservoirs from Enhong and Laochang Districts, Yunnan[J]. Geological Journal of China Universities, 2012, 18(3): 516-521(in Chinese).

Google Scholar

[9] Y.B. Yao, D.M. Liu, W.H. Huang, et al. Research on the pore-fracture system properties of coalbed methane reservoirs and recovery in Huainan and Huaibei coal-fields [J]. Journal of china coal society, 2006, 31(2): 163-168(in Chinese).

Google Scholar

[10] S.H. Zhang, D.Z. Tang, S.H. Tang, et al. Preservation and deliverability characteristics of coalbed methane in east margin of Ordos Basin. Journal of China Coal Society, 2009, 34(10): 1297-1304(in Chinese).

Google Scholar

[11] J.P. Li, D.Z. Tang, H. Xu, et al. Analysis on gas drainage features and influence factors of low-rank coalbed methane well[J]. Coal science and technology, 2013, 41(12): 53-56(in Chinese).

Google Scholar

[12] GB/T 212-2008, 2008. Chinese national standard. Coal, Proximate analysis of coal(in Chinese).

Google Scholar

[13] ISO 7404. 3-1994, 1994. Methods for the petrographic analysis of bituminous coal and anthracite-Part 3: method of determining maceral group composition.

DOI: 10.3403/00115055

Google Scholar

[14] ISO 15901. 2-2006, 2006. Pore size distribution and porosity of solid materials by mercury porosimetry and gas adsorption—Part 2: analysis of mesopores and macropores by gas adsorption.

DOI: 10.3403/30116588

Google Scholar

[15] Y.B. Yao, D.M. Liu, Y. Che, et al. Petrophysical characterization of coals by low-field nuclear magnetic resonance (NMR). Fuel, 2010, 89: 1371–80.

DOI: 10.1016/j.fuel.2009.11.005

Google Scholar

[16] ASTM D 388-99, 2005. Annual Book of ASTM Standards. Gaseous Fuels; Coal and Coke, vol. 05. 06. Standard Classification of Coals by Rank.

Google Scholar

[17] B.B. Hodot. Outburst of coal and coalbed gas[M]. 1966. Beijing: China Industry Press.

Google Scholar

[18] D.M. Liu, Y.B. Yao, D.Z. Tang, et al. Coal reservoir characteristics and coalbed methane resource assessment in Huainan and Huaibei Coalfields, Southern North China[J]. International Journal of Coal Geology, 2009, 79(3): 97-112.

DOI: 10.1016/j.coal.2009.05.001

Google Scholar

[19] Y.B. Yao, D.M. Liu. Comparison of low-field NMR and mercury intrusion porosimetry in characterizing pore size distributions of coals [J]. Fuel, 2012, 95: 152-158.

DOI: 10.1016/j.fuel.2011.12.039

Google Scholar

[20] G. Pickett. Modification of the Brunauer–Emmett–Teller theory of multimolecular adsorption. Journal of the American Chemical Society, 1945, 67: 1958-(1962).

DOI: 10.1021/ja01227a027

Google Scholar

[21] E.P. Barrett, L.G. Joyner, P.P. Halenda. The determination of pore volume and area distributions in porous substances. Journal of the American Chemical Society, 1951, 73: 373-380.

DOI: 10.1021/ja01145a126

Google Scholar

[22] W.P. Jiang, X.Z. Song, L.W. Zhong, et al. Research on the pore properties of different coal body structure coals and the effects on gas outburst based on the low-temperature nitrogen adsorption method [J]. Coal science and technology, 2011, 36(4): 609-614(in Chinese).

Google Scholar

[23] P. Chen, X.Y. Tang. The research on the adsorption of nitrogen in low temperature and micro- pore properties in coal[J]. Journal of China Coal Society, 2001, 26(5): 552-556(in Chinese).

Google Scholar

[24] H. Xu, D.Z. Tang, D.M. Liu, et al. Study on coalbed methane accumulation characteristics and favorable areas in the Binchang area, southwestern Ordos Basin, China [J]. International Journal of Coal Geology, 2012, 95: 1-11.

DOI: 10.1016/j.coal.2012.02.001

Google Scholar

[25] C.G.V. Burgess, D.H. Everett, and S. Nuttall. Adsorption hysteresis in porous materials. Pure and Applied Chemistry, 1989, 61: 1845-1852.

DOI: 10.1351/pac198961111845

Google Scholar

[26] S. Tao, Y.B. Wang, D.Z. Tang, et al. Pore and structure systems and their contribution to the permeability of coal reservoirs in southern Qinshui Basin. Geological Journal of China Universities, 2012, 18(3): 522-527(in Chinese).

Google Scholar

[27] Z.H. Chen, C.Z. Jia, Y. Song, et al. Differences and origin of physical properties of low-rank and high-rank coal-bed methanes[J]. Acta Petrolei Sinica. 2008, 29(2): 179-184 (in Chinese).

Google Scholar

[28] C.R. Clarkson and R.M. Bustin. The effect of pore structure and gas pressure upon the transport properties of coal: a laboratory and modeling study. 1. Isotherms and pore volume distributions [J]. Fuel, 1999, 78(11): 1333-1344.

DOI: 10.1016/s0016-2361(99)00055-1

Google Scholar