Processability Behaviour of Dual Filler Systems Reinforced Epoxised Natural Rubber

Article Preview

Abstract:

Rheological studies of polymers are of great importance in optimizing the processing conditions and in designing processing equipments like injection molding machines, extruders, and dies required for various products. Melt rheological studies give us valuable viscosity data that will be helpful in optimizing the processing conditions. Parameters like melt viscosity as a function of shear rate or shear stress and temperature have become more and more important. Previous study indicated that the flow behaviour of the compound depends on the filler loading. Lesser elastic torque was found with compound containing lower filler content as compared to higher filler content. In this work, effect of dual filler, based on Carbon Black / Silica filled Epoxidised Natural Rubber (ENR) compound was investigated. A total of 80phr of filler content based on passenger tyre tread formulation was used in the experiment. The compounds were prepared by melt mixing in tangential type of an internal mixer. The rheological and the processability properties of the compounds were determined using three different testing instruments namely Capillary Rheometer, Mooney viscometer and Rubber Process Analyzer (RPA). A variation of shear rates (ranging from low to high) was performed, in order to better reflect the actual processing condition in rubber manufacturing. It was found that ENR mix with ratio silica to carbon black 70:10 exhibited the best flow behaviour and processability properties as compared to control and other mixes.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

195-198

Citation:

Online since:

June 2014

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Brydson, J. A. Flow Properties of Polymer Melts, 2nd Ed., London: George Godwin. (1981).

Google Scholar

[2] Wood, A. K., Read, A. G. G. and Lovegrove, J. G. A. Effect of Rheometer Design on the Measurement of the Flow Properties of Polymer Melts. Plast. Rubber Process Appl. 1989; 12(1), 15-20.

Google Scholar

[3] Leblanc, J. L. (1981) Studies of Rubber Processability using A New Automated Capillary Rheometer. Plast. Rubbber Process Appl., 1(2), 187-193.

Google Scholar

[4] ISO 289-1. Determinations Using a Shearing Disc Viscometer-Part 1: Determination of Mooney Viscosity, International Organisation for Standardisation. (2005).

DOI: 10.3403/30134938

Google Scholar

[5] Carreau, P. J., De Kee, D. C. R. and Chabra, R. P. (1997) Rheology of Polymeric Systems: Principles and Applications, New York: Hanser, p.61–71.

Google Scholar

[6] Meng-Jiao Wang, Phing Zhang & Khalid Mahmud. Carbon-Silica Dual Phase Filler, A New Generation Reinforcing Agent for Rubber Part IX, Application to Truck Tire Tread Compound. Rubber Division, ACS, Dallas, Texas. 2000; April 4 – 6.

DOI: 10.5254/1.3547633

Google Scholar

[7] Stephane Schaal And Aubert Y. Coran. The Rheology and Processability of Tire Compounds. Rubber Chemistry and Technology. 2000; Vol 73, 225-239.

DOI: 10.5254/1.3547587

Google Scholar