Structural and Magnetoelectric Properties of a New W-Type Hexaferrite (Sr0.85Ce0.15Co2Fe16O27-δ)

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A new W-type hexaferrite (Sr0.85Ce0.15Co2Fe16O27-δ) was synthesized through proteic sol-gel using coconut water as a solvent for the precursor salts. Structural analysis was carried out using an X-ray diffractometer (XRD). The XRD results showed that the resulting ceramic exhibited preferential orientations along the crystal planes in addition to lattice displacements. The magnetic properties evaluated using a vibrating sample magnetometer indicated a high saturation magnetization value and low coercive field and remnant magnetization values. The Curie temperature determined through differential scanning calorimetry was 473 oC. The electric resistivity value determined through complex impedance was similar to those already reported in the literature, thus promising the use of this hexaferrite in electronic and microwave device applications.

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263-267

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July 2014

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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[1] R. C. Pullar, Hexagonal ferrites: A review of the synthesis, properties and applications of hexaferrite ceramics, Progress in Materials Science 57 (2012) 1191–1334.

DOI: 10.1016/j.pmatsci.2012.04.001

Google Scholar

[2] S. O. Al- Asbahi, R. M. Kershi, The X-ray Diffraction Microstructure Analysis of Hexagonal Ferrite Powders Doped with La Rare Earth Ions. J Chem Crystallogr 42 (2012) 155–158.

DOI: 10.1007/s10870-011-0217-1

Google Scholar

[3] I. Sadiq, I. Khan, F. Aen, M.U. Islam, M.U. Rana, Influence of rare earth Ce3+ on structural, electrical and magnetic properties of Sr2+ based W-type hexagonal ferrites, Physica B 407 (2012) 1256–1261.

DOI: 10.1016/j.physb.2012.01.115

Google Scholar

[4] I. Khana, I. Sadiqa, M. N. Ashiqb, M. Rana, Role of Ce–Mn substitution on structural, electrical and magnetic properties of W-type strontium hexaferrites, Journal of Alloys and Compounds 509 (2011) 8042– 8046.

DOI: 10.1016/j.jallcom.2011.05.013

Google Scholar

[5] I. Khan, M. N. Ashiq, I. Sadiq, A. M. Qureshi, M. U. Rana, Effect of Ce Substitution on Structural and Electrical Properties of W-type Strontium Hexaferrite Nanomaterials, Journal of the Chemical Society of Pakistan, 34 (2012) 579-583.

Google Scholar

[6] Z. W. Li, C. K. Ong, Z. Yang, F. L. Wei, X. Z. Zhou, J. H. Zhao, A. H. Morrish, Site preference and magnetic properties for a perpendicular recording material: BaFe12-xZnx/2Zrx/2O19 nanoparticles, Phys. Rev. B 62 (2000) 6530-6537.

DOI: 10.1103/physrevb.62.6530

Google Scholar

[7] M. J. Iqbal, R. A. Khan, S. Mizukami, T. Miyazaki, Mössbauer, magnetic and microwave absorption characteristics of substituted W-type hexaferrite nanoparticles, Ceramics International 38 (2012) 4097-4103.

DOI: 10.1016/j.ceramint.2012.01.067

Google Scholar

[8] M. Ohmura, H. Yamamoto Effect of Co Stearate Addition on Magnetic Properties of Anisotropic SrFe2 W-Type Ferrite Magnets IEEE Trans Magn 40 (2004) 1695-1702.

DOI: 10.1109/tmag.2004.826908

Google Scholar

[9] M.J. Iqbal, R.A. Khan, Enhancement of electrical and dielectric properties of Cr-doped BaZn2 W-Type hexaferrite for potential applications in high frequency devices, J. Alloys & Compounds, 478 (2009) 847-852.

DOI: 10.1016/j.jallcom.2008.12.084

Google Scholar

[10] M. J. Iqbalw, F. Liaqat, Physical and Electrical Properties of Nanosized Mn- and Cr-Doped Strontium Y-Type Hexagonal Ferrites, J. Am. Ceram. Soc. 93 (2010) 474–480.

DOI: 10.1111/j.1551-2916.2009.03385.x

Google Scholar