The Effect of Doping Lanthanum on Phlogopite-Iron Pearlescent Pigments

Article Preview

Abstract:

Mica-based pearlescent pigments are widely applied in plastics, cosmetics, automobiles coatings and other fields, but very few applications in high temperature field are found as their poor heat resistance. In this paper, phlogopite is chosen as a new substrate which is coated by Fe2O3 (doping with La3+) in order to improve the high temperature resistance and luster of the new developed pearlescent pigments. According to the X-ray diffraction (XRD) and scanning electron microscopy (SEM) results, it is found that Fe2O3 nanospheres were coated on the surface of phlogopite homogenously. Colorimeter data imply that doping La3+ can improve the color saturation and purity of pigments apparently. And the optimum amount is 3% lanthanum nitrate addition in this work.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

161-164

Citation:

Online since:

July 2014

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Pfaff G, Reynders P, Angle-dependent optical effects deriving from submicron structures of films and pigments, Chem Rev, 99(1999): 1963-(1982).

DOI: 10.1021/cr970075u

Google Scholar

[2] Hao H, Xiong G and Tang Z et al. Research and application of mica pearlescent pigments, Dyestuff industry, 35(1998): 23–26.

Google Scholar

[3] Tan J R, Fu X S and Hou W X et al. The preparation and characteristics of a multi-cover-layer type, blue mica titania, pearlescent pigment, Dyes and Pigments, 56(2003): 93–98.

DOI: 10.1016/s0143-7208(02)00103-1

Google Scholar

[4] Smith H.M. High Performance Pigments, Wiley-VCH, New York, (2002).

Google Scholar

[5] Zhang G K, Wan H W. The preparation of blue mica pearlescent pigments, Conservation and utilization of mineral resource, 1(1998): 20-23.

Google Scholar

[4] Cavalcante P M T, Dondi M, Guarini G et al. Ceramic application of mica titania pearlescent pigments, Dyes and Pigments, 74(2007): 1-8.

DOI: 10.1016/j.dyepig.2006.01.026

Google Scholar

[6] Cai W X, Li D G, Fu W Q, O Y P. Preparation of titanium-mica pearlescent pigment doped with tinny-oxides and discussion on optical poperties thereof, Inorganic chemicals industry, 42(2010): 26-28.

Google Scholar

[7] Chen J, Shi X B, Han B. The preparation and characteristics of cobalt blue colored mica titania pearlescent pigment by microemulsions, Dyes and Pigments, 75(2007): 766-769.

DOI: 10.1016/j.dyepig.2006.08.020

Google Scholar

[8] Ren D G, Meng H M, Xian C J et al. Application of Pearly Pigment of Mica Titanium, Equipment environment engineering, 4(2007): 81-84.

Google Scholar

[9] Ren M, Yin H B et al, Evolution of TiO2 coating layers on lamellar sericite in the presence of La3+ and the pigmentary properties. Applied Surface Science, 254(2008): 7314–7320.

DOI: 10.1016/j.apsusc.2008.05.325

Google Scholar

[10] Glausch R, Kieser M, Maisch R et al. Special effect pigments. Hannover: Vincentz, (1998).

Google Scholar

[11] Sun G X, Li Y H, Ge Q X et al. Research on Preparation and Properties of Ferric Oxide-phlogopite Pearly Pigment. Non-Metallic Mines, 35(2012): 52-54.

Google Scholar