Synthesis, Characterization and Photophysical Properties of Rhenium(I) Complexe with 2-(naphthalen-2-yl)-1-phenyl-1H-imidazo[4,5-f][1,10]phenanthroline

Qiang Li; Le Li; Rong Feng Zhong; Hai Di Cai; Feng Zhao

doi:10.4028/www.scientific.net/AMR.988.66

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HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 988Synthesis, Characterization and Photophysical...

Synthesis, Characterization and Photophysical Properties of Rhenium(I) Complexe with 2-(naphthalen-2-yl)-1-phenyl-1H-imidazo[4,5-f][1,10]phenanthroline

Abstract:

In this paper, a Re(I) complex [Re(CO)₃(E2)Cl], where E2 = 2-(naphthalen-2-yl)-1-phenyl-1H-imidazo[4,5-f][1,10]phenanthroline(E2), was synthesized and characterized by ¹H NMR successfully. Experimental data confirm that Re(I) complex [Re(CO)₃(E2)Cl] is high-energy-emitting one. The broad band emission upon excitation at λ = 400 nm with the emission maximum locates at λ = 581 nm in solid state and 614nm in CH₂Cl₂ solution were observed.

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Advanced Materials Research (Volume 988)

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66-69

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https://doi.org/10.4028/www.scientific.net/AMR.988.66

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July 2014

Authors:

Qiang Li*, Le Li, Rong Feng Zhong, Hai Di Cai, Feng Zhao

Keywords:

10-Phenanthroline, Photoluminescence (PL), Rhenium(I) Complex

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