Preparation of Visible-Light Active Mn-Doped TiO2 Photocatalyst and its Photodegradation of Methylene Blue from Solution

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Mn-doped TiO2 nanocrystal photocatalysts were prepared by the sol-gel method using MnSO4·H2O as manganese source. The catalysts were characterized by XRD, SEM, EPR, UV-Vis, their photocatalytic activity for methylene blue (MB) degradation was investigated. The results showed that Mn was doped into the crystal lattice of TiO2, and had no influence on TiO2 crystal structure; the size of TiO2 nanoparticle gradually decreased with Mn doping concentration increasing. The Mn-doped TiO2 catalysts have enhanced absorption in the visible light region, and its visible light absorptivity increased with Mn doping concentration increasing. The UV-Vis showed the Mn-doped TiO2 showed higher photocatalytic activity than the undoped TiO2 for methylene blue degradation under visible light irradiation. It is also found that the MB photodegradation rate of Mn-doped TiO2 improved by 46% than that of the undoped TiO2.

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Advanced Materials Research (Volumes 989-994)

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531-535

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July 2014

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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