3D Printing of Urethane Dimethacrylate with Nanoclay for Enhanced Curing Properties via Stereolithography

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Stereolithography (SLA) is a 3D printing technology that stands out because of its high dimensional accuracy and resolution, excellent surface finish, versatile modification of feedstock chemistry, and low cost of its printers. SLA uses an ultraviolet laser to trace and illuminate a light pattern onto a layer of photocurable resin. However, its disadvantages are the requirement of support structures, use of hazardous resins, the feedstock is limited to curable materials, and the need for a faster curing time. This study aims to improve the curing time of acrylate-based photopolymer resin by adding nanoclay as an additive. Different concentrations of nanoclay, 1wt%, 3wt%, and 5wt%, were added to urethane dimethacrylate, and their curing behavior and mechanical properties were determined. In this study, 3wt% was the ideal concentration since it had better mechanical properties than the control and exhibited the best curing characteristic. This further confirmed that nanoclay is a favorable additive in the 3D printing of acrylate-based photopolymers, solving the concern for fabrication speed and enhancing the mechanical properties of the photopolymer.

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59-64

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September 2024

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© 2024 Trans Tech Publications Ltd. All Rights Reserved

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[1] Y. Mao, Z. Ding, C. Yuan, S. Ai, M. Isakov, J. Wu, T. Wang, M.L. Dunn, H.J. Qi, 3D Printed Reversible Shape Changing Components with Stimuli Responsive Materials, Scientific Reports. 6 (2016).

DOI: 10.1038/srep24761

Google Scholar

[2] H. Eng, S. Maleksaeedi, S. Yu, Y.Y.C. Choong, F.E. Wiria, R.E. Kheng, J. Wei, P.C. Su, H.P. Tham, Development of CNTs-filled photopolymer for projection stereolithography, RapidPrototyping Journal.23(2017)129–136.https://doi.org/10.1108/RPJ-10-2015- 0148.

DOI: 10.1108/rpj-10-2015-0148

Google Scholar

[3] J.R. Tumbleston, D. Shirvanyants, N. Ermoshkin, R. Janusziewicz, A.R. Johnson, D. Kelly, K. Chen, R. Pinschmidt, J.P. Rolland, A. Ermoshkin, E.T. Samulski, J.M. DeSimone, Continuous liquid interface production of 3D objects, Science. 347 (2015) 1349–1352.

DOI: 10.1126/science.aaa2397

Google Scholar

[4] Y.Y.C. Choong, S. Maleksaeedi, H. Eng, S. Yu, J. Wei, P.C. Su, High speed 4D printing of shape memory polymers with nanosilica, Applied Materials Today. 18 (2020).

DOI: 10.1016/j.apmt.2019.100515

Google Scholar

[5] A. Sun, X. He, X. Ji, D. Hu, M. Pan, L. Zhang, Z. Qian, Current research progress of photopolymerized hydrogels in tissue engineering, Chinese Chemical Letters. 32 (2021) 2117–2126.

DOI: 10.1016/j.cclet.2021.01.048

Google Scholar

[6] H. Quan, T. Zhang, H. Xu, S. Luo, J. Nie, X. Zhu, Photo-curing 3D printing technique and its challenges, Bioactive Materials. 5 (2020) 110–115.

DOI: 10.1016/j.bioactmat.2019.12.003

Google Scholar

[7] A. Bagheri, J. Jin, Photopolymerization in 3D Printing, ACS Applied Polymer Materials. 1 (2019) 593–611.

DOI: 10.1021/acsapm.8b00165

Google Scholar

[8] Wang, Y., Blache, R., & Xu, X. (2017). Selection of additive manufacturing processes. Rapid Prototyping Journal, 23(2), 434–447.

DOI: 10.1108/rpj-09-2015-0123

Google Scholar

[9] Mohsen, N. M., Craig, R. G., & Filisko, F. E. (1998). Effects of curing time and filler concentration on curing and postcuring of urethane dimethacrylate composites: A microcalorimetric study. Journal of Biomedical Materials Research, 40(2), 224–232. doi:10.1002/(sici)1097-4636(199805)40:2<224::aid-jbm7>3.0.co;2-n.

DOI: 10.1002/(sici)1097-4636(199805)40:2<224::aid-jbm7>3.3.co;2-i

Google Scholar

[10] Sideridou, I. D., & Achilias, D. S. (2005). Elution study of unreacted Bis-GMA, TEGDMA, UDMA, and Bis-EMA from light-cured dental resins and resin composites using HPLC. Journal of Biomedical Materials Research Part B: Applied Biomaterials, 74B(1), 617–626.

DOI: 10.1002/jbm.b.30252

Google Scholar

[11] Lempel, E., Czibulya, Z., Kovács, B., Szalma, J., Tóth, Á., Kunsági-Máté, S., Böddi, K. (2016). Degree of Conversion and BisGMA, TEGDMA, UDMA Elution from Flowable Bulk Fill Composites. International Journal of Molecular Sciences, 17(5), 732.

DOI: 10.3390/ijms17050732

Google Scholar

[12] Guerra, R. M., Duran, I., & Ortiz, P. (2008). FTIR monomer conversion analysis of UDMA-based dental resins. Journal of Oral Rehabilitation, 23(9), 632–637.

DOI: 10.1111/j.1365-2842.1996.tb00903.x

Google Scholar

[13] R.N. Jones, "Infrared Spectra of Organic Compounds: Summary Charts of Principal Group Frequencies", NRC Bulletin, [6], 1959.

Google Scholar

[14] Zare, Y., & Rhee, K. Y. (2020). Simulation of Young's modulus for clay-reinforced nanocomposites assuming mechanical percolation, clay-interphase networks and interfacial linkage. Journal of Materials Research and Technology, 9(6), 12473–12483.

DOI: 10.1016/j.jmrt.2020.08.097

Google Scholar

[15] Savage, D., Wilson, J., Benbow, S., Sasamoto, H., Oda, C., Walker, C., … Tachi, Y. (2019). Natural systems evidence for the effects of temperature and the activity of aqueous silica upon montmorillonite stability in clay barriers for the disposal of radioactive wastes.

DOI: 10.1016/j.clay.2019.105146

Google Scholar

[16] Nguyen, J.-F., Pomes, B., Sadoun, M., & Richaud, E. (2019). Curing of urethane dimetracrylate composites: A glass transition study. Polymer Testing, 80, 106113. doi:10.1016/j.polymertesting. 2019.106113.

DOI: 10.1016/j.polymertesting.2019.106113

Google Scholar